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Front cover pg X001; DOI: 10.1039/P198800FX001 |
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Contents pages pg P001; DOI: 10.1039/P198800FP001 |
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Ring lithiation of pyridones Premji Meghani and John A. Joule pg 1; DOI: 10.1039/P19880000001 |
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Back cover pg X003; DOI: 10.1039/P198800BX003 |
Syntheses of  -(R)- and -(S)-lipoic acid from (S)-malic acidMichael H. Brookes Bernard T. Golding and Alan T. Hudson pg 9; DOI: 10.1039/P19880000009 |
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Macrocyclic and macropolycyclic compounds based upon 1,3-disubstituted propane units John A. E. Pratt Ian O. Sutherland and Roger F. Newton pg 13; DOI: 10.1039/P19880000013 |
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Synthesis of 13-steroids. A new route to 16-substituted 13-androstanes Jean-Paul Auclair and Jean-Claude Gramain pg 23; DOI: 10.1039/P19880000023 |
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Inter-and intra-molecular photocycloaddition of enol ethers to naphthalene Andrew Gilbert Peter Heath Annoula Kashoulis-Koupparis Graham C. R. Ellis-Davies and Susan M. Firth pg 31; DOI: 10.1039/P19880000031 |
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Stilbene glycosides from Guibourtia coleosperma: determination of glycosidic connectivities by homonuclear nuclear Overhauser effect difference spectroscopy Jan P. Steynberg E. Vincent Brandt Johann F. W. Burger Barend C. B. Bezuidenhoudt and Daneel Ferreira pg 37; DOI: 10.1039/P19880000037 |
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Chemistry of 2-bromo-2-methylpropanamides. Synthesis and solvolytic behaviour of oxazolidinones and spiro-oxazolidinones Paolo Scrimin Giorgio Cavicchioni Ferruccio D'Angeli Amiram Goldblum and Flavio Maran pg 43; DOI: 10.1039/P19880000043 |
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A novel hydroxylactone from the Lewis acid catalysed pyrolysis of cellulose Richard H. Furneaux Jennifer M. Mason and Ian J. Miller pg 49; DOI: 10.1039/P19880000049 |
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An efficient route to triene synthons for putative intermediates in polyether antibiotic biosynthesis Ulrich. C. Dyer and John A. Robinson pg 53; DOI: 10.1039/P19880000053 |
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The synthesis and rotational isomerism of 1-amino-2-imidazol-4-ylethylphosphonic acid [phosphonohistidine, His(P)] and 1-amino-2-imidazol-2-ylethylphosphonic acid [phosphonoisohistidine, Isohis(P)] John H. Merrett William C. Spurden W. Anthony Thomas Brian P. Tong and Ian W. A. Whitcombe pg 61; DOI: 10.1039/P19880000061 |
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Intramolecular nitrene insertions into aromatic and heteroaromatic rings. Part 8. Flash vacuum pyrolysis of 2-azidobenzylpyridines Martin G. Hicks Gurnos Jones and David C. York pg 69; DOI: 10.1039/P19880000069 |
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Synthesis of novel macrocyclic lactones with potential pharmacological activity Keith Smith Ian K. Morris Philip G. Owen and Robert J. Bass pg 77; DOI: 10.1039/P19880000077 |
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Enantiospecific synthesis of the spiroacetal moieties of avermectins A1b, B1b, A1a, B1a, A2b, B2b, A2a, and B2a and milbemycins 7 and 8 Raymond Baker John C. Head and Christopher J. Swain pg 85; DOI: 10.1039/P19880000085 |
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Retrodienic reactions. Part 2. Vinyl- and propenyl-phosphines: synthesis by flash vacuum thermolysis and characterization Marie-Claire Lasne Jean-Louis Ripoll and André Thuillier pg 99; DOI: 10.1039/P19880000099 |
Neighbouring group participation on the bromination of methyl gibberellate: X-ray molecular structure of methyl 3,13-di-O-acetylgibberellate 16 ,17-dibromide and ent-3,13-diacetoxy-17-bromo-10,16-dihydroxy-20-norgibberell-1-ene-7,19-dioic acid 19,10-lactone 7-methyl esterIsidro G. Collado Braulio M. Fraga James R. Hanson Peter B. Hitchcock and Fernando G. Tellado pg 105; DOI: 10.1039/P19880000105 |
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Synthesis of (L)-daunosamine and related amino sugars Peter G. Sammes and Dean Thetford pg 111; DOI: 10.1039/P19880000111 |
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Chemistry of bis-spiroacetals. Synthesis of the 1,6,8-trioxadispiro[4.1.5.3]pentadecane ring system Raymond Baker and Margaret A. Brimble pg 125; DOI: 10.1039/P19880000125 |
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Instructions for authors (1988) pg v; DOI: 10.1039/P1988000000v |
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IUPAC publications on nomenclature and symbolism pg xx; DOI: 10.1039/P198800000xx |
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Refereeing procedure and policy (1988) pg xxiv; DOI: 10.1039/P1988000xxiv |
Issue 2
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Front cover pg X005; DOI: 10.1039/P198800FX005 |
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Contents pages pg P005; DOI: 10.1039/P198800FP005 |
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Back cover pg X007; DOI: 10.1039/P198800BX007 |
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Heterocycles from carbohydrate precursors. Part 40. Kinetic and thermodynamic products of ketalation of 1-C-substituted L-threo-glycerol: a regioselective formation of 1,3-dioxolanes El Sayed H. El Ashry Yeldez El Kilany and Farrag Singab pg 133; DOI: 10.1039/P19880000133 |
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Heterocycles from carbohydrate precursors. Part 41. Mode of formation of 1,3-dioxolanes and 1,3-dioxanes from 1-C-substituted glycerols during their benzylidenation El Sayed H. El Ashry Yeldez El Kilany and Ahmed Mousaad pg 139; DOI: 10.1039/P19880000139 |
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Nucleophilic attack on 4,7-disubstituted benzofurazans and their N-oxides: synthesis of tetrazolo[1,5-a]azepines James G. Belton and R. Stanley McElhinney pg 145; DOI: 10.1039/P19880000145 |
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Reaction of 1,2-benzoquinones with enamines Yoshimori Omote Atsushi Tomotake and Choji Kashima pg 151; DOI: 10.1039/P19880000151 |
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A new eudesmenolide and 2-hydroxycostic acid from Sphaeranthus indicus linn. X-Ray molecular structure of 4,5-epoxy-7-hydroxyeudesmanolide Jayant S. Sohoni Supada R. Rojatkar Mandakini M. Kulkarni Narayandatta N. Dhaneshwar Sudam S. Tavale Tayur N. Gururow and Bhimsen A. Nagasampagi pg 157; DOI: 10.1039/P19880000157 |
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The synthesis and chemistry of azolenines. Part 8. The Paal-Knorr reaction with cyclic 2-(acylmethyl)-2-alkyl-1,3-diketones: isolation of 1-acyl-1H-pyrroles via rearrangement Prem Nath Maini Michael P. Sammes and Alan R. Katritzky pg 161; DOI: 10.1039/P19880000161 |
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Polarized ketene S,S- and S,N-acetals. Part 52. Lead tetra-acetate oxidation of 3-anilino-3-methylthio-2-arylacrylonitriles. A novel approach to substituted indoles Jai Narain Vishwakarma Abraham Thomas Satyam Apparao Hiriyakkanavar Ila and Hiriyakkanavar Junjappa pg 169; DOI: 10.1039/P19880000169 |
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Oxo-phospholes from the alkoxyphosphonium ylides formed in the reaction of trialkyl phosphites or dialkyl phosphonites with dimethyl acetylenedicarboxylate Julian C. Caesar D. Vaughan Griffiths and John C. Tebby pg 175; DOI: 10.1039/P19880000175 |
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Preparation of deuteriated 1-phenylethanols by reductive dehalogenation of the corresponding halogenoacetophenones with Raney alloys in an alkaline deuterium oxide solution Masashi Tashiro Shuntaro Mataka Hiroshi Nakamura and Kouji Nakayama pg 179; DOI: 10.1039/P19880000179 |
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Retention of stereochemistry in the ring-opening of penicillin V sulphone p-nitrobenzyl ester Michael Davis and Wen-Yang Wu pg 183; DOI: 10.1039/P19880000183 |
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Photochemical and thermal reactions of heterocycles. Part 5. Products via transient quasiantiaromatic azetine intermediates generated by desulphurisation of photochemical intermediates from a thiazolium-4-olate and 4-aminothiazolium salts Hiroshi Kato Kozo Wakao Akira Yamada and Yasuhiro Mutoh pg 189; DOI: 10.1039/P19880000189 |
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Synthesis of aromatic sesquiterpenes, ()-cuparene and ()-laurene by means of an intramolecular carbenoid displacement (ICD) reaction Tetsuji Kametani Kuniaki Kawamura Masayoshi Tsubuki and Toshio Honda pg 193; DOI: 10.1039/P19880000193 |
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Reactions involving fluoride ion. Part 34. Stable perfluorinated carbanions Andrew E. Bayliff and Richard D. Chambers pg 201; DOI: 10.1039/P19880000201 |
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N.m.r. and conformational studies on some 1,3-linked disaccharides Herbert Baumann Per-Erik Jansson and Lennart Kenne pg 209; DOI: 10.1039/P19880000209 |
[2 ,2]-(+)-Catechin-(+)-taxifolin from commercial willow bark: structure, bonding positions and oxidative cleavageHerbert Kolodziej pg 219; DOI: 10.1039/P19880000219 |
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Contrasting reactions of 2,6-dichloro-4-trichloromethylpyridine, 2,6-dichloro-3-trichloromethylpyridine and their N-oxides with nucleophiles Ronald S. Dainter Hans Suschitzky Basil J. Wakefield Nigel Hughes and Anthony J. Nelson pg 227; DOI: 10.1039/P19880000227 |
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A new route to 1-oxygenated carbazoles. Synthesis of the carbazole alkaloids murrayafoline-A and murrayaquinone-A Tracey Martin and Christopher J. Moody pg 235; DOI: 10.1039/P19880000235 |
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Synthesis of the carbazole alkaloid murrayaquinone-B Tracey Martin and Christopher J. Moody pg 241; DOI: 10.1039/P19880000241 |
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A new precursor to 3,4-didehydropyridine, and its use in the synthesis of the antitumour alkaloid ellipticine Christopher May and Christopher J. Moody pg 247; DOI: 10.1039/P19880000247 |
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Mechanisms for reactions of halogenated compounds. Part 5. Orientating effects of fluorine substituents on nucleophilic substitution in naphthalene and other polycyclic systems Richard D. Chambers Mark J. Seabury D. Lyn H. Williams and Nigel Hughes pg 251; DOI: 10.1039/P19880000251 |
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Mechanisms for reactions of halogenated compounds. Part 6. Investigations into the activating effect of ortho-fluorine in nucleophilic aromatic substitution Richard D. Chambers Mark J. Seabury D. Lyn H. Williams and Nigel Hughes pg 255; DOI: 10.1039/P19880000255 |
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Regioselective chlorination of valine derivatives Nigel J. Bowman Michael P. Hay Stephen G. Love and Christopher J. Easton pg 259; DOI: 10.1039/P19880000259 |
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Regioselective formation of amidocarboxy-substituted free radicals Christopher J. Easton Michael P. Hay and Stephen G. Love pg 265; DOI: 10.1039/P19880000265 |
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Reactions of metallated 1,3-dithianes with carboxylic acid derivatives Philip C. Bulman Page Monique B. van Niel and Donald Westwood pg 269; DOI: 10.1039/P19880000269 |
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Allenes. Part 46. Synthesis of 1,2-dihydro-4H-3,1 -benzoxazines, 4H-3,1-benzoxazines, and 3-cyanoquinolines from allenic and acetylenic nitriles Z. Tanee Fomum A. Ephraim Nkengfack Stephen R. Landor and Phyllis D. Landor pg 277; DOI: 10.1039/P19880000277 |
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Both-faces hindered porphyrins. Part 4. Synthesis of functionalized basket-handle porphyrins designed for a strict intramolecular axial ligation in superstructured complexes Michel Momenteau Bernard Loock Christiane Huel and Jean-Marc Lhoste pg 283; DOI: 10.1039/P19880000283 |
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-Diketone interactions. Part 6. X-Ray molecular structure of 3-(4-methoxyphenyl)pentane-2,4-dione, a -diketone enol tautomer with a very strong hydrogen bond John Emsley Neville J. Freeman Paul A. Bates and Michael B. Hursthouseb pg 297; DOI: 10.1039/P19880000297 |
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New co-metabolites of gliotoxin in Gliocladium virens Gordon W. Kirby Ghanakota V. Rao and David J. Robins pg 301; DOI: 10.1039/P19880000301 |
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General method for the asymmetric synthesis of -amino acids via alkylation of the chiral nickel(II) Schiff base complexes of glycine and alanine Yuri. N. Belokon Vladimir I. Bakhmutov Nina I. Chernoglazova Konstantin A. Kochetkov Sergei V. Vitt Natalia S. Garbalinskaya and Vasili M. Belikov pg 305; DOI: 10.1039/P19880000305 |
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Coenzyme models. Part 45. Synthesis of atropisomeric flavins and their novel redox-induced racemisation Seiji Shinkai Hideki Nakao Itsuko Kuwahara Megumi Miyamoto Toshiro Yamaguchi and Osamu Manabe pg 313; DOI: 10.1039/P19880000313 |
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Photo-induced molecular transformations. Part 87. Regiospecific photo-Beckmann rearrangement of steroidal ,-unsaturated ketone oximes: synthesis of some steroidal enamino lactams Hiroshi Suginome Makoto Kaji and Shinji Yamada pg 321; DOI: 10.1039/P19880000321 |
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Reduction of 1-(2-hydroxy-3,5-di-t-butylphenyl)pyridinium halides and their zwitterions. Formation of di- and tetra-hydropyrido[2,1-b]benzoxazoles Gouki Fukata Takashi Itoh Shuntaro Mataka and Masashi Tashiro pg 327; DOI: 10.1039/P19880000327 |
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Thermolysis of polyazapentadienes. Part 8. The formation of pyrroles from 1,1-dialkyl-5-aryl-1,5-diazapentadienes Hamish McNab and M. Elizabeth-Ann Murray pg 333; DOI: 10.1039/P19880000333 |
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Thermolysis of polyazapentadienes. Part 9. Gas phase thermolyses of some dienamines, enaminones, and enaminothiones Clare L. Hickson and Hamish McNab pg 339; DOI: 10.1039/P19880000339 |
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Studies on the mechanism of lysine 2,3-aminomutase D. John Aberhart pg 343; DOI: 10.1039/P19880000343 |
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Synthesis, molecular structure, and reactions of 1H-1,2,4-triazolo[4,3-a]pyrimidinium betaines Hugh Marley Kevin J. McCullough Peter N. Preston and Stanley H. B. Wright pg 351; DOI: 10.1039/P19880000351 |
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Excitatory amino acids. Improved synthesis of ibotenic acid and X-ray analysis of an unexpected reaction product,(RS)-N-[2-(3-benzyloxyisoxazol-5-yl)-1-phenylethyl]-3-oxobutyramide Uif Madsen Lotte Brehm and Povi Krogsgaard-Larsen pg 359; DOI: 10.1039/P19880000359 |
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Solid state and solution conformation of phenylacetyl-L-cysteinyl-D-penicillamine cyclic disulphide methyl ester; a cyclic dipeptide containing a trans amide Robert L. Baxter Steven S. B. Glover Eric M. Gordon Robert O. Gould Marion C. McKie A. Ian Scott and Malcolm D. Walkinshaw pg 365; DOI: 10.1039/P19880000365 |
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Enantioselective synthesis of the tricyclo[5.2.2.0]undecane skeleton using aprotic Michael-additions; formal total synthesis of (+)-lsoeremolactone Dietrich Spitzner and Gisela Sawitzki pg 373; DOI: 10.1039/P19880000373 |
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Structure elucidation of longikaurin A and longikaurin B, new biologically active diterpenoids from Rabdosia longituba and chemical conversion of oridonin into dihydrolongikaurin A Yoshio Takeda Tetsuro Fujita and Tetsuro Shingu pg 379; DOI: 10.1039/P19880000379 |
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Synthesis and properties of methano-bridged tetradehydro-[26]-, -[28]-, -[30]-, -[32]-, -[34]-, and -[38]-annulene J  ro Ojima Satoshi Fujita Masayuki Masumoto Emiko Ejiri Tadahito Kato Shigeyasu Kuroda Yoshihiko Nozawa Shuji Hirooka Yoshiharu Yoneyama and Hitoshi Tatemitsu pg 385; DOI: 10.1039/P19880000385 |
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Synthesis and properties of methano-[12]-, -[18]-, -[20]-, -[22]-, -[24]-annulene and dimethano-[20]- and -[24]-annulene Koji Yamamoto Shigeyasu Kuroda Mitsuo Shibutani Yoshiharu Yoneyama J ro Ojima Satoshi Fujita Emiko Ejiri and Kazuhiro Yanagihara pg 395; DOI: 10.1039/P19880000395 |
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Pyridazine chemistry. Part 33. 5-Aminopyridazin-4-yl o-fluorophenyl ketone as a key intermediate in the syntheses of diaza analogues of acridone, xanthone, and thioxanthone Norbert Haider and Gottfried Heinisch pg 401; DOI: 10.1039/P19880000401 |
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Studies on medicinal and related plants of Sri Lanka. Part 18. Structure of a new naphthoquinone from Plumbago zeylanica. G. M. Kamal B. Gunaherath A. A. Leslie Gunatilaka and Ronald H. Thomson pg 407; DOI: 10.1039/P19880000407 |
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Reactions of trimethylsilyl ketene acetals with benzoyl cyanide and with - keto esters Chaganti P. Reddy and Shigeo Tanimoto pg 411; DOI: 10.1039/P19880000411 |
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Additions and corrections Sadao Arai Tsuneo Takeuchi Masanori Ishikawa Tatsuo Takeuchi Masuo Yamazaki Mitsuhiko Hida Kenso Soai Hideaki Machida and Noriko Yokota pg 415; DOI: 10.1039/P19880000415 |
Issue 3
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Front cover pg X009; DOI: 10.1039/P198800FX009 |
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Contents pages pg P009; DOI: 10.1039/P198800FP009 |
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Back cover pg X011; DOI: 10.1039/P198800BX011 |
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Asymmetric syntheses. Part 2. Reduction of ketones with chiral sodium borohydride-lactic acid derivative systems Giorgio Bianchi Fiorella Achilli Anna Gamba and Dina Vercesi pg 417; DOI: 10.1039/P19880000417 |
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Synthesis and spectral properties of chemically and stereochemically homogeneous sphingomyelin and its analogues Karol S. Bruzik pg 423; DOI: 10.1039/P19880000423 |
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Stereoselective cyclizations of unsaturated esters derived from 2,3-O-isopropylidene-D-ribose Michael G. B. Drew Peter D. Kane John Mann and Mahbuba Naili pg 433; DOI: 10.1039/P19880000433 |
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Karounidiol [D:C-friedo-oleana-7,9(11)-diene-3,29-diol] and its 3-o-benzoate: novel pentacyclic triterpenes from Trichosanthes kirilowii. X-Ray molecular structure of karounidiol diacetate Toshihiro Akihisa Toshitake Tamura Taro Matsumoto Drake S. Eggleston W. C. M. C. Kokke and Naoto Shimizu pg 439; DOI: 10.1039/P19880000439 |
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Synthetic studies on terpenoid compounds. Part 14. Total synthesis of pyroangolensolide Takashi Tokoroyama Yoshiyasu Fukuyama and Yasuhito Kotsuji pg 445; DOI: 10.1039/P19880000445 |
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Cycloadditions of 3H-indoles David J. Le Count and Anthony P. Marson pg 451; DOI: 10.1039/P19880000451 |
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10-Chloro-17-hydroxyestra-1,4-dien-3-one and its related compounds Fumikazu Mukawa pg 457; DOI: 10.1039/P19880000457 |
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Stereospecific synthesis of squalenoid epoxide vinyl ethers as inhibitors of 2,3-oxidosqualene cyclase Maurizio Ceruti Franca Viola Franco Dosio Luigi Cattel Pierrette Bouvier-Navé and Piero Ugliengo pg 461; DOI: 10.1039/P19880000461 |
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Synthetic studies towards the pinguisanes; synthesis of 4-epi-pinguisone Raymond Baker David L. Selwood Christopher J. Swain Nigel M. H. Webster and Jordan Hirshfield pg 471; DOI: 10.1039/P19880000471 |
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An efficient synthesis of ()-latifine dimethyl ether Vinayak G. Gore and Nurani S. Narasimhan pg 481; DOI: 10.1039/P19880000481 |
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Initiation mechanisms in radical polymerization: reaction of t-butoxy radicals with allyl acrylate and with diallyl ether W. Ken Busfield Ian D. Jenkins San H. Thang Ezio Rizzardo and David H. Solomon pg 485; DOI: 10.1039/P19880000485 |
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Photo-induced molecular transformations. Part 87. Ring expansion through [2 + 2] photocycloaddition--scission sequences; synthesis of benzohomotropones from 1- and 2-naphthols and methyl acrylate Hiroshi Suginome Masahito Itoh and Kazuhiro Kobayashi pg 491; DOI: 10.1039/P19880000491 |
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Preparation and 11C-labelling of a Substance P analogue containing D-tryptophan in positions 7 and 9 Henry M. Franzén Kjell Någren Leif Grehn Bengt Långström and Ulf Ragnarsson pg 497; DOI: 10.1039/P19880000497 |
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Secondary mould metabolites. Part 19. Structure elucidation and absolute configuration of melledonals B and C, novel antibacterial sesquiterpenoids from Armillaria mellea. X-Ray molecular structure of melledonal C Alberto Arnone Rosanna Cardillo Gianluca Nasini and Stefano Valdo Meille pg 503; DOI: 10.1039/P19880000503 |
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Synthesis and characterization of crowned 1,4-benzoquinones as ionophore-dienophile (redox) combined systems: double interaction with catecholamines and tryptamine Kenji Hayakawa Keiko Kido and Ken Kanematsu pg 511; DOI: 10.1039/P19880000511 |
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Reaction of phenylnitrenium ion with sulphides. A novel synthetic method for aminophenyl sulphide derivatives Hiroshi Takeuchi Shinji Hirayama Michiharu Mitani and Kikuhiko Koyama pg 521; DOI: 10.1039/P19880000521 |
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Convenient synthesis of mixed anhydrides by the ozonolysis of oxazoles Choji Kashima Shigeki Hibi Kazuo Harada and Yoshimori Omote pg 529; DOI: 10.1039/P19880000529 |
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Amino alcohols as C-terminal protecting groups in peptide synthesis Choji Kashima Kazuo Harada Yoko Fujioka Tatsuya Maruyama and Yoshimori Omote pg 535; DOI: 10.1039/P19880000535 |
X Y–ZH systems as potential 1,3-dipoles. Part 9. Aza-allyl anion precursors from the reaction of (1,3-dioxoindan-2-ylidene)malononitrile with -amino acids and their methyl estersRonald Grigg and Theeravat Mongkolaussavaratana pg 541; DOI: 10.1039/P19880000541 |
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New methodology for C-nucleoside synthesis: preparation of 1,2-dideoxy-1-(3-pyridyl)-D-ribofuranose Michael A. W. Eaton T. Andrew Millican and John Mann pg 545; DOI: 10.1039/P19880000545 |
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Use of diethylaminosulphur trifluoride (DAST) in the preparation of synthons of carbocyclic nucleosides Keith Biggadike Alan D. Borthwick Derek Evans Anne M. Exall Barrie E. Kirk Stanley M. Roberts Les Stephenson and Peter Youds pg 549; DOI: 10.1039/P19880000549 |
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Reactions of tetrafluoroethene oligomers. Part 7. Some reactions of 4-diazo-1,1,1,2,2-pentafluoro-3-pentafluoroethyl-3-trifluoromethylbutane Paul L. Coe Michael I. Cook Nicholas J. Goodchild and Philip N. Edwards pg 555; DOI: 10.1039/P19880000555 |
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Synthesis of 2,3-dialkyl-6,7-dichloro- and 2,3-dialkyl-6,7-dibromo-1,4-naphthoquinones Alamdar Ashnagar J. Malcolm Bruce and Paul Lloyd-Williams pg 559; DOI: 10.1039/P19880000559 |
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Studies on fluoroalkylation and fluoroalkoxylation. Part 28. Palladium(0)-induced addition of fluoroalkyl iodides to alkenes: an electron transfer process Qing-Yun Chen Zhen-Yu Yang Cheng-Xue Zhao and Zai-Ming Qiu pg 563; DOI: 10.1039/P19880000563 |
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Organic synthesis with carbon monoxide: the synthesis of carbamoylstannanes and aromatic carbamoylation Charles M. Lindsay and David A. Widdowson pg 569; DOI: 10.1039/P19880000569 |
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Reaction of olefins with Se-phenyl (selenothioperoxy)benzoate: a new anti-Markownikoff benzeneselenenylation Takeshi Toru Takuya Seko Eturô Maekawa and Yoshio Ueno pg 575; DOI: 10.1039/P19880000575 |
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Autoxidation of naphthols: a new entry to the perylene system José S. Calderon and Ronald H. Thomson pg 583; DOI: 10.1039/P19880000583 |
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Total synthesis of cortisol: application to selective deuteriation at C-1 and C-19 Kazuo Minagawa Takashi Furuta Yasuji Kasuya Akiharu Fujino Mitchell A. Avery and Masato Tanabe pg 587; DOI: 10.1039/P19880000587 |
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Syntheses and properties of some polymethylene-bridged adenines Kazuharu Ienaga Taisuke Hasegawa Desmond J. Brown and Wolfgang Pfleiderer pg 593; DOI: 10.1039/P19880000593 |
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The regiochemistry and stereochemistry of 1,3-dipolar cycloaddition of a cyclic nitrone Sk. Asrof Ali and Mohammed I. M. Wazeer pg 597; DOI: 10.1039/P19880000597 |
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Studies of pyrimidine-2,4-diones: synthesis of novel condensed pyrido[2,3-d]pyrimidines via intramolecular cycloadditions Dipak Prajapati Pulakjyoti Bhuyan and Jagir Singh Sandhu pg 607; DOI: 10.1039/P19880000607 |
Role of remote heteroatoms and nature of the reducing agents on the stereochemical course of reductions of the carbon–nitrogen  -bond of a new class of tetrahydropyridinesSwaraj B. Maiti Swadesh R. Raychaudhuri Amareshwar Chatterjee and Ajit K. Chakravarty pg 611; DOI: 10.1039/P19880000611 |
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Thermal Claisen rearrangement studies on 4,6- and 2,4-diacetylresorcinol bisallyl ethers: observation of loss or [1,5] sigmatropic shift of acetyl groups Ammanamanchi S. R. Anjaneyulu and Uppuluri V. Mallavadhani pg 623; DOI: 10.1039/P19880000623 |
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Chiroptical properties and molecular geometry of substituted succinic anhydrides and imides Tadeusz Po  o ski pg 629; DOI: 10.1039/P19880000629 |
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Circular dichroism spectra and molecular geometry of six-membered ring anhydrides and imides Tadeusz Po oski pg 639; DOI: 10.1039/P19880000639 |
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Enantioselective synthesis of (3S)-trans-4-(substituted methyl)monobactams from 2,3-O-isopropylidene-D-glyceraldehyde Rosario Herranz Santiago Conde Piedad Fernández-Resa and Enrique Arribas pg 649; DOI: 10.1039/P19880000649 |
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New germacrane derivatives from Nanothamnus sericeous. X-Ray molecular structure of (1R,4R,5R,6R,10R)-1,10;4,5-diepoxy-11-hydroxygermacran-6-yl (Z)-2-methylbut-2-enoate Uppoor G. Bhat Vedavati G. Puranik Narayandatt N. Dhaneshwar Sudam S. Tavale Tayur N. Guru Row and Bhimsen A. Nagasampagi pg 657; DOI: 10.1039/P19880000657 |
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Synthetic approaches to the thiathromboxanes. Part 1. Preparation of functionalised dihydrothiopyrans Kevin R. Lawson Brian P. McDonald Owen S. Mills Robert W. Steele James K. Sutherland Trevor J. Wear Andrew Brewster and Peter R. Marsham pg 663; DOI: 10.1039/P19880000663 |
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Synthetic approaches to thiathromboxanes. Part 2. Synthesis of structural isomers of thiathromboxane A2 Brian P. McDonald Robert W. Steele James K. Sutherland Bruce W. Leslie and Andrew Brewster pg 675; DOI: 10.1039/P19880000675 |
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o-Nitroaniline derivatives. Part 9. Benzimidazole N-oxides unsubstituted at N-1 and C-2 Ian W. Harvey Michael D. McFarlane David J. Moody and David M. Smith pg 681; DOI: 10.1039/P19880000681 |
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o-Nitroaniline derivatives. Part 10. 5- and 6-Amino-1H-benzimidazole 3-oxides Michael D. McFarlane David J. Moody and David M. Smith pg 691; DOI: 10.1039/P19880000691 |
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Liquid–liquid and solid–liquid phase-transfer glycosylation of pyrrolo[2,3-d]pyrimidines: stereospecific synthesis of 2-deoxy--D-ribofuranosides related to 2-deoxy-7-carbaguanosine Frank Seela Bernhard Westermann and Uwe Bindig pg 697; DOI: 10.1039/P19880000697 |
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Borohydride-enhanced dechlorination of chlorobenzenes and toluenes Gary A. Epling and Emily M. Florio pg 703; DOI: 10.1039/P19880000703 |
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Phosphorylated sugars. Part 24. Methyl 3-deoxy--D-manno-oct-2-ulopyranosidonic acid 4-(dihydrogen phosphate): synthesis, stability in acidic medium, and colorimetric estimation S. Robert Sarfati Annick Le Dur and Ladislas Szabó pg 707; DOI: 10.1039/P19880000707 |
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Petuniasterones, novel ergostane-type steroids of Petunia hybridia Vilm. (Solanaceae) having insect-inhibitory activity. X-Ray molecular structure of the 22,24,25-[(methoxycarbonyl)orthoacetate] of 7,22,24,25-tetrahydroxy ergosta-1,4-dien-3-one and of 1-acetoxy-24,25-epoxy-7-hydroxy-22-(methylthiocarbonyl)acetoxyergost-4-en-3-one Carl A. Elliger Mabry E. Benson William F. Haddon Robert E. Lundin Anthony C. Waiss Jr. and Rosalind Y. Wong pg 711; DOI: 10.1039/P19880000711 |
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Synthesis of novel carbo- and hetero-polycycles. Part 7. Synthesis of 6-azatricyclo[6.3.1.0]dodecane and 5-azatricyclo[5.3.1.1]dodecane derivatives via intramolecular cycloaddition of N-{(endo-bicyclo[3.3.1]non-6-en-3-yl)methyl}nitrones Shoji Eguchi Yoshio Furukawa Takanori Suzuki and Tadashi Sasaki pg 719; DOI: 10.1039/P19880000719 |
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Synthesis of tetrahydropyrimidines with 2-oxoalkyl groups using pyrimidinium salts and enol silyl ethers: formation of diazabicyclo[3.3.1]nona-3,6-diene derivatives Yohsuke Yamamoto Akira Sakaguchi Hiroshi Yoshida and Kin-ya Akiba pg 725; DOI: 10.1039/P19880000725 |
Issue 4
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Front cover pg X013; DOI: 10.1039/P198800FX013 |
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Contents pages pg P013; DOI: 10.1039/P198800FP013 |
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Back cover pg X015; DOI: 10.1039/P198800BX015 |
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Synthetic methods. Part 23. Rearrangement of some hydroxamic acids into amides. A self-condensation leading to disproportionation Alfred Hassner Margareta Ruse Hugo E. Gottlieb and Miriam Cojocaru pg 733; DOI: 10.1039/P19880000733 |
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Application of a modified Pictet–Spengler reaction to the synthesis of optically active tetrahydro--carbolines, key intermediates in the preparation of many indole alkaloids Patrick D. Bailey and Sean P. Hollinshead pg 739; DOI: 10.1039/P19880000739 |
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Biosynthesis of canescin, a metabolite of Aspergillus malignus: incorporation of methionine, acetate, succinate, and isocoumarin precursors, labelled with deuterium and carbon-13 Christopher N. Lewis James Staunton and David C. Sunter pg 747; DOI: 10.1039/P19880000747 |
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An investigation of the biosynthesis of citromycetin in Penicillium frequentans using 13C- and 14C-labelled precursors Geoffrey E. Evans and James Staunton pg 755; DOI: 10.1039/P19880000755 |
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Isolation and structure elucidation of polivione, a polyketide co-metabolite of citromycetin in Penicillium frequentans Agathi K. Demetriadou Ernest D. Laue Finian J. Leeper and James Staunton pg 763; DOI: 10.1039/P19880000763 |
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A study of biosynthesis of the polyketide polivione in Penicillium frequentans using 13C-, 2H-, and 18O-labelled precursors Agathi K. Demetriadou Ernest D. Laue and James Staunton pg 769; DOI: 10.1039/P19880000769 |
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Biosynthesis of palitantin, a polyketide metabolite of Penicillium brefeldianum: 13C n.m.r. assignment and incorporation of 13C-, 2H-, and 18O2-labelled acetates Agathi K. Demetriadou Ernest D. Laue and James Staunton pg 773; DOI: 10.1039/P19880000773 |
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No-carrier-added radiobromination and radioiodination of aromatic rings using in situ generated peracetic acid Stephen M. Moerlein Werner Beyer and Gerhard Stöcklin pg 779; DOI: 10.1039/P19880000779 |
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Identification of the absolute stereochemistry of D- and L-oleandroses using a chiral h.p.l.c. column Sachiko Tsukamoto Koji Hayashi Kô Kaneko and Hiroshi Mitsuhashi pg 787; DOI: 10.1039/P19880000787 |
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Reaction of isoxazoles and isoxazolium salts with organometallic reagents. Synthesis of dihydroisoxazoles Angel Albertola Luis Fernando Antolín Ana González Miguel Angel Laguna and Francisco José Pulido pg 791; DOI: 10.1039/P19880000791 |
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A formylation–cyclisation method of synthesis of cycloalkenones from unsaturated ketones. Part 3. Simple synthesis of some functionalised angularly fused cyclopentenone and cyclopentanone derivatives Brindaban C. Ranu Ratna Chakraborti and Usha Ranjan Ghatak pg 795; DOI: 10.1039/P19880000795 |
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Thermally induced rearrangement of thiopheniobis(alkoxycarbonyl)methanides Timothy Bowles Roger J. Gillespie Alexander E. A. Porter Josef A. Rechka and Henry S. Rzepa pg 803; DOI: 10.1039/P19880000803 |
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Thermally induced rearrangement of thiopheniobis(alkoxycarbonyl)methanides. A theoretical MNDO SCF-MO study Alexander E. A. Porter and Henry S. Rzepa pg 809; DOI: 10.1039/P19880000809 |
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-Thio-substituted ketones as precursors of olefins via oxathiolanes: -methoxybenzyl as protecting group Michael D. Brown Catherine J. Meunier and Gordon H. Whitham pg 813; DOI: 10.1039/P19880000813 |
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-Thio-substituted ketones as precursors of olefins via oxathiolanes: benzyl as protecting group Michael D. Brown and Gordon H. Whitham pg 817; DOI: 10.1039/P19880000817 |
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Metabolites of the higher fungi. Part 23. The punctaporonins. Novel bi-, tri-, and tetra-cyclic sesquiterpenes related to caryophyllene, from the fungus Poronia punctata(Linnaeus:Fries) Fries John R. Anderson Raymond L. Edwards J. Philip Poyser and Anthony J. S. Whalley pg 823; DOI: 10.1039/P19880000823 |
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A novel synthesis of pyrrolizidine alkaloids by means of an intramolecular carbenoid displacement (ICD) reaction Tetsuji Kametani Hirotaka Yukawa and Toshio Honda pg 833; DOI: 10.1039/P19880000833 |
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Synthesis of averufin and its role in aflatoxin B1 biosynthesis Craig A. Townsend Siegfried B. Christensen and Steven G. Davis pg 839; DOI: 10.1039/P19880000839 |
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3-Hydroxypyrroles and 1H-pyrrol-3(2H)-ones. Part 2. Scope and limitations of the synthesis of pyrrol-3-ones by pyrolysis of aminomethylene Meldrum's acid derivatives Hamish McNab and Lilian C. Monahan pg 863; DOI: 10.1039/P19880000863 |
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3-Hydroxypyrroles and 1H-pyrrol-3(2H)-ones. Part 3. Pyrrolones from pyrolyses of aminomethylene Meldrum's acid derivatives: loss of chirality at the site of hydrogen transfer Hamish McNab and Lilian C. Monahan pg 869; DOI: 10.1039/P19880000869 |
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Peracid oxidation of 16-arylidene- and 16-alkylidene-17-oxo-steroids Lameck S. Chagonda and Brian A. Marples pg 875; DOI: 10.1039/P19880000875 |
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The structure of leudrin, and the nucleophilic substitution of its primary hydroxy group by bromine Guido W. Perold Laurence Carlton Arthur S. Howard and Joseph P. Michael pg 881; DOI: 10.1039/P19880000881 |
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A novel route to the des-A corticosteroids Hideo Nemoto Mari Moizumi Mitsuo Nagai Keiichiro Fukumoto and Tetsuji Kametani pg 885; DOI: 10.1039/P19880000885 |
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N.m.r. and conformational studies of some 1,4-linked disaccharides Irene Backman Bertil Erbing Per-Erik Jansson and Lennart Kenne pg 889; DOI: 10.1039/P19880000889 |
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The synthesis and properties of some novel 5-amino-1,4,2-dithiazolium salts and the X-ray molecular structure of 5-morpholino-3-(4-nitrophenyl)-1,4,2-dithiazolium fluoroborate Florence S. Y. Chan Michael P. Sammes and Richard L. Harlow pg 899; DOI: 10.1039/P19880000899 |
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Studies on fungal products. Part 15. Isolation and structure determination of arugosin E from Aspergillus silvaticus and cycloisoemericellin from Emericella striata Nobuo Kawahara Koohei Nozawa Shoichi Nakajima and Ken-ichi Kawai pg 907; DOI: 10.1039/P19880000907 |
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Chemistry of biotin: access to 2,3- and 5,6-didehydrobiotin derivatives Robert L. Baxter and Andrew Coutts pg 913; DOI: 10.1039/P19880000913 |
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1,3-Dipolar character of six-membered aromatic rings. Part 56. The cycloadditions of acetylenes and 3-oxidopyridinium betaines Christina Y. Ishag Keith J. Fisher Badr Eldin Ibrahim George M. Iskander and Alan R. Katritzky pg 917; DOI: 10.1039/P19880000917 |
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Sodium perfluoroalkane carboxylates as sources of perfluoroalkyl groups Gillian E. Carr Richard D. Chambers Thomas F. Holmes and David G. Parker pg 921; DOI: 10.1039/P19880000921 |
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Stereoselective addition of lithium amides to activated triple bonds Ben-Ami Feit Shulamit Dickerman Djamal Masrawe and Ariela Fishman pg 927; DOI: 10.1039/P19880000927 |
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Total synthesis of ()-pisiferic acid Ajoy Kumar Banerjee Héctor S. Hurtado Manuel M. Laya Julio C. Acevedo and Jaime G. Alvárez pg 931; DOI: 10.1039/P19880000931 |
Vinylogous Wolff rearrangement of cyclic , -unsaturated diazomethyl ketones: a new synthetic method for angularly functionalised polycyclic systemsBijali Saha Gopa Bhattacharjee and Usha Ranjan Ghatak pg 939; DOI: 10.1039/P19880000939 |
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Reaction of silylimines with ester enolates. Synthesis of N-unsubstituted azetidinones starting from nitriles Patrizia Andreoli Gianfranco Cainelli Michele Contento Daria Giacomini Giorgio Martelli and Mauro Panunzio pg 945; DOI: 10.1039/P19880000945 |
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XY–ZH systems as potential 1,3-dipoles. Part 10. The decarboxylative route to azomethine ylides. Background and relevance to pyridoxal decarboxylases Moustafa F. Aly Ronald Grigg Sunit Thianpatanagul and Visuvanathar Sridharan pg 949; DOI: 10.1039/P19880000949 |
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Photochemistry of pyrimidin-2(1H)-ones: intermolecular hydrogen abstraction by an imino group nitrogen Takehiko Nishio and Yoshimori Omote pg 957; DOI: 10.1039/P19880000957 |
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Cyclobutarenes. Part 3. Synthesis of bromodicyclobutarenes and some new derivatives of the benzocyclobutabiphenylenes Michael K. Shepherd pg 961; DOI: 10.1039/P19880000961 |
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Indolization by phosphorus trichloride of functionalized ketone arylhydrazones: synthesis of pharmacological interesting indoles Grazieno Baccolini Renato Dalpozzo and Paolo E. Todesco pg 971; DOI: 10.1039/P19880000971 |
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Allenes. Part 47. Pyrido[1,2-a]pyrimidines and their hydrolysis products from allenic and acetylenic nitriles Stephen R. Landor Phyllis D. Landor Andrew Johnson Z. Tanee Fomum J. Tanyi Mbafor and A. Ephraim Nkengfack pg 975; DOI: 10.1039/P19880000975 |
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Corrigendum Jill Gigg Roy Gigg Sheila Payne Robert Conant José Barluenga José M. Martinez-Gallo Carmen Nájera Francisco J. Fañanás and Miguel Yus pg 981; DOI: 10.1039/P19880000981 |
Issue 5
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Front cover pg X017; DOI: 10.1039/P198800FX017 |
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Contents pages pg P017; DOI: 10.1039/P198800FP017 |
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Back cover pg X019; DOI: 10.1039/P198800BX019 |
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2H-benzimidazoles (isobenzimidazoles). Part 2. Synthesis and reactions of 5-azido-2H-benzimidazole-2-spirocyclohexane Hans Suschitzky Walter Kramer Richard Neidlein and Helmut Uhl pg 983; DOI: 10.1039/P19880000983 |
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2H-benzimidazoles (isobenzimidazoles). Part 3. Thermal isomerisation of substituted 2H-benzimidazoles to 1H-benzimidazoles John A. L. Herbert Brian Iddon Andrew G. Robinson and Hans Suschitzky pg 991; DOI: 10.1039/P19880000991 |
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A synthesis of (2S,6S)-2-hydroxymethyl-6-methoxytetrahydropyran; a useful chiral intermediate Keith Jones and William W. Wood pg 999; DOI: 10.1039/P19880000999 |
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Biosynthesis of diisocyanoadociane, a novel diterpene from the marine sponge Amphimedon sp. Crystal structure of a monoamide derivative Christopher J. R. Fookes Mary J. Garson John K. MacLeod Brian W. Skelton and Allan H. White pg 1003; DOI: 10.1039/P19880001003 |
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Novel base-induced reactions of substituted (1,2-benzisoxazol-3-yl)acetates Sh  z Ueda Shunsuke Naruto Toyokichi Yoshida Tadahiro Sawayama and Hitoshi Uno pg 1013; DOI: 10.1039/P19880001013 |
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Synthesis of some thiophenium bis(t-butoxycarbonyl)methylides Timothy Bowles Ray Jones Alexander E. A. Porter Josef A. Rechka Henry S. Rzepa and David J. Williams pg 1023; DOI: 10.1039/P19880001023 |
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Regio- and stereo-selective synthesis of -sulphonyl-,-unsaturated carbonyl compounds via an iodosulphonylation–dehydroiodination reaction Carmen Nájera Beatriz Baldó and Miguel Yus pg 1029; DOI: 10.1039/P19880001029 |
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Synthesis of benzimidazolyl selenophenes Zoltàn Zubovics and Làszlò Hevesi pg 1033; DOI: 10.1039/P19880001033 |
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Titanium as a regio- and stereo-selective control element in the reaction of -alkoxyallylic phosphine oxide anions with carbonyl compounds Ewan F. Birse Alexander McKenzie and Alistair W. Murray pg 1039; DOI: 10.1039/P19880001039 |
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Synthesis of novel carbo- and hetero-polycycles. Part 8. An efficient and convenient synthesis of adamantylidenevinylidenecyclopropane derivatives Shoji Eguchi and Motohiro Arasaki pg 1047; DOI: 10.1039/P19880001047 |
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Thioesters of amino acid derivatives as thioacylating agents in thiopeptide synthesis Donald T. Elmore David J. S. Guthrie Gillian Kay and Carrell H. Williams pg 1051; DOI: 10.1039/P19880001051 |
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Synthesis of 5,9,9-trisubstituted 1-azabicyclo[3.3.1]nonanes and their conformational analyses Seiji Miyano Michiko Irie Nobuko Mibu Yasuhiko Miyamoto Kiyofumi Nagata and Kunihiro Sumoto pg 1057; DOI: 10.1039/P19880001057 |
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Acid-catalysed rearrangements of steroid alkenes. Part 1. Rearrangement of 5-cholest-7-ene Torren M. Peakman and James R. Maxwell pg 1065; DOI: 10.1039/P19880001065 |
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Acid-catalysed rearrangements of steroid alkenes. Part 2. A re-investigation of the backbone rearrangement of cholest-5-ene Torren M. Peakman Karen Ellis and James R. Maxwell pg 1071; DOI: 10.1039/P19880001071 |
Total synthesis of ()- 9(12)-capnellene-8,10-diolGerald Pattenden and Simon J. Teague pg 1077; DOI: 10.1039/P19880001077 |
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Synthetic radical chemistry. Total synthesis of ()-isoamijiol Michael J. Begley Gerald Pattenden and Graeme M. Robertson pg 1085; DOI: 10.1039/P19880001085 |
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Intramolecular free radical cyclisations onto enol ethers. A general synthesis of -alkyl--oxy- and -methylene--oxy--butyrolactones Michael J. Begley Mark Ladlow and Gerald Pattenden pg 1095; DOI: 10.1039/P19880001095 |
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Radical additions onto enols and enol ethers as a stratagem in synthesis. Total synthesis of the unique epoxy-lactone ()-alliacolide found in Marasmius alliaceus Mark Ladlow and Gerald Pattenden pg 1107; DOI: 10.1039/P19880001107 |
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A total synthesis of allamcin. An approach to antileukaemic iridoid lactones and formal syntheses of plumericin and allamandin Kevin E. B. Parkes and Gerald Pattenden pg 1119; DOI: 10.1039/P19880001119 |
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Simple and condensed -lactams. Part 9. Elaboration of the 3-(1-hydroxyethyl) side chains of potential intermediates of carbapenem antibiotics via the 2-methyl-1,3-dioxolan-2-yl group József Fetter Károly Lempert Mária Kajtár-Peredy and Gyula Simig pg 1135; DOI: 10.1039/P19880001135 |
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Synthesis of 9a-deoxymitomycin congeners Yoshinori Naruta Naoshi Nagai and Kazuhiro Maruyama pg 1143; DOI: 10.1039/P19880001143 |
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Chemistry of novel compounds with multifunctional carbon structure. Part 3. Synthesis of -azido--fluoro--(phenylthio and ethylthio)acetates Yoshio Takeuchi Masahiro Asahina Kozo Hori and Toru Koizumi pg 1149; DOI: 10.1039/P19880001149 |
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Stereocontrolled synthesis of the CDF part of Aconitum alkaloids via intramolecular double Michael reaction Masataka Ihara Yohhei Ishida Mariko Abe Masahiro Toyota Keiichiro Fukumoto and Tetsuji Kametani pg 1155; DOI: 10.1039/P19880001155 |
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Pyrrolizidine alkaloid analogues. Synthesis of 11-membered macrocyclic diesters of (+)-heliotridine Desmond B. Hagan and David J. Robins pg 1165; DOI: 10.1039/P19880001165 |
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Pyrrolizidine alkaloid analogues. Synthesis of macrocyclic diesters of ()-synthanecine A from ()-3-chloromethyl-2-hydroxymethyl-1-methyl-2,5-dihydropyrrolium chloride Robert H. Barbour and David J. Robins pg 1169; DOI: 10.1039/P19880001169 |
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Compounds with bridgehead nitrogen. Part 54. The stereochemistry of some derivatives of perhydrothiazolo[3,4-a]pyridine and the synthesis of 9-methylperhydro-3,8-methano-1,3-thiazocines Trevor A. Crabb Andrew N. Trethewey and Yoshito Takeuchi pg 1173; DOI: 10.1039/P19880001173 |
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Trifluoromethanethiolate ion. Part 3. Reactions with tetrafluoropyridazine and tetrafluoropyrimidine Wojciech Dmowski and Alois Haas pg 1179; DOI: 10.1039/P19880001179 |
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Synthesis and nuclear magnetic resonance studies of some N-acylated methyl 4-amino-4,6-dideoxy--D-mannopyranosides Lennart Kenne Per Unger and Thomas Wehler pg 1183; DOI: 10.1039/P19880001183 |
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Biosynthesis of porphyrins and related macrocycles. Part 30. Synthesis of the macrocycle of the spiro system proposed as an intermediate generated by cosynthetase W. Marshall Stark Mark G. Baker Finian J. Leeper Paul R. Raithby and Alan R. Battersby pg 1187; DOI: 10.1039/P19880001187 |
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Fluorination of pyrimidines. Part 2. Mechanistic aspects of the reaction of acetyl hypofluorite with uracil and cytosine derivatives Gerard W. M. Visser Renella E. Herder Frans J. J. de Kanter and Jacobus D. M. Herscheid pg 1203; DOI: 10.1039/P19880001203 |
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Syntheses and reactions of 9-substituted 10-phenylthioxanthenium salts: negative evidence for thia-anthracene oligomerisation Mikio Hori Tadashi Kataoka Hiroshi Shimizu Megumi Ikemori and Yasuko Aoyama pg 1209; DOI: 10.1039/P19880001209 |
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Preparation of 4-amino hexopyranose nucleosides from keto nucleosides. An approach to amino nucleoside antibiotics Jean Herscovici Marie-José Egron and Kostas Antonakis pg 1219; DOI: 10.1039/P19880001219 |
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Oligomeric isoflavonoids. Part 1. Structure and synthesis of the first (2,3)-isoflavone-isoflavan dimer Barend C. B. Bezuidenhoudt E. Vincent Brandt Jacobus A. Steenkamp David G. Roux and Daneel Ferreira pg 1227; DOI: 10.1039/P19880001227 |
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Oligomeric isoflavonoids. Part 2. Structure and synthesis of xanthocercin A and B, the first isoflavono-lignoids S. Catherine Bezuidenhout Barend C. B. Bezuidenhoudt E. Vincent Brandt and Daneel Ferreira pg 1237; DOI: 10.1039/P19880001237 |
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Acid-catalysed terpenylations of olivetol in the synthesis of cannabinoids Leslie Crombie W. Mary L. Crombie Sally V. Jamieson and Christopher J. Palmer pg 1243; DOI: 10.1039/P19880001243 |
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Terpenylations using (R)-(–)--phellandrene. Synthesis of the (3S,4R)-8,9-dihydro-o- and -p-cannabidiols, their iso-THC's, and the natural dihydrochalcone (3S,4R)-(+)-linderatin Leslie Crombie W. Mary L. Crombie and David F. Firth pg 1251; DOI: 10.1039/P19880001251 |
Synthesis of cannabinoids carrying  -carboxy substituents: the cannabidiols, cannabinol and 1- and 6-tetrahydrocannabinols of this seriesLeslie Crombie W. Mary L. Crombie and Patoomratana Tuchinda pg 1255; DOI: 10.1039/P19880001255 |
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Synthesis of bibenzyl cannabinoids, hybrids of two biogenetic series found in Cannabis sativa Leslie W. Crombie W. Mary L. Crombie and David F. Firth pg 1263; DOI: 10.1039/P19880001263 |
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Reactivity of malononitrile towards sulphamide and N-substituted sulphamides: synthesis and hydrolysis reactions of 3,5-diamino-1,2,6-thiadiazine 1,1-dioxides Ibon Alkorta Vicente J. Arán Agustín G. Bielsa and Manfred Stud pg 1271; DOI: 10.1039/P19880001271 |
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Total synthesis of hydrocinchonidine and hydrocinchonine via photo-oxygenation of an indole derivative Masataka Ihara Nobuaki Taniguchi Kazuharu Noguchi Keiichiro Fukumoto and Tetsuji Kametani pg 1277; DOI: 10.1039/P19880001277 |
Issue 6
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Front cover pg X021; DOI: 10.1039/P198800FX021 |
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Contents pages pg P021; DOI: 10.1039/P198800FP021 |
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Back cover pg X023; DOI: 10.1039/P198800BX023 |
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Studies on the mechanism of polyketide-derived biosynthesis of deoxyradicinin and related metabolites of Alternaria helianthi Beni Tal Gwendolyn Goldsby Basil A. Burke Arne J. Aasen and David J. Robeson pg 1283; DOI: 10.1039/P19880001283 |
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Syntheses of macrocyclic enzyme models. Part 6. Preparation and guest-binding behaviour of octopus cyclophanes Yukito Murakami Jun-ichi Kikuchi Masashi Suzuki and Takeo Matsuura pg 1289; DOI: 10.1039/P19880001289 |
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Regioreversed nucleophilic substitution of 2-(allyloxy)benzothiazole by allylic Grignard reagents. A regioselective synthesis of 1,5-dienes Vincenzo Calo Luigi Lopez and Giannangelo Pesce pg 1301; DOI: 10.1039/P19880001301 |
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Phenanthrene-4,5-quinones: a synthesis of morphenol Frank R. Hewgill and Jeffery M. Stewart pg 1305; DOI: 10.1039/P19880001305 |
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Photochemical behaviour of some 1,2,4-oxadiazole derivatives Silvestre Buscemi Maria G. Cicero Nicoló Vivona and Tullio Caronna pg 1313; DOI: 10.1039/P19880001313 |
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Cyclopalladiated aromatic imines in organic synthesis: the preparation of cinnamonitriles, cinnamates, unsymmetrical stilbenes, isoquinolones, and isoquinolines Ian R. Girling and David A. Widdowson pg 1317; DOI: 10.1039/P19880001317 |
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Oligomeric flavanoids. Part 1. Novel dimeric profisetinidins from Colophospermum mopane Jacobus A. Steenkamp Johannes C. S. Malan David G. Roux and Daneel Ferreira pg 1325; DOI: 10.1039/P19880001325 |
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The synthesis of di- and tri-arylamines through halogen displacement by base-activated arylamines: comparison with the Ullmann condensation John H. Gorvin pg 1331; DOI: 10.1039/P19880001331 |
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Starfish saponins. Part 34. Novel steroidal glycoside sulphates from the starfish Asterias amurensis Raffaele Riccio Maria Iorizzi Luigi Minale Yasukatsu Oshima and Takeshi Yasumoto pg 1337; DOI: 10.1039/P19880001337 |
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Total syntheses of marine sponge metabolites. Part 3. Stereoselective total synthesis of ()-12-deoxyscalaradial Tatsuhiko Nakano María Isabel Hernández Alfonso Martín and José Domingo Medina pg 1349; DOI: 10.1039/P19880001349 |
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Synthesis and photolysis of 4-thioxoazetidin-2-ones Masami Sakamoto Michiyo Tanaka Akiko Fukuda Hiromu Aoyama and Yoshimori Omote pg 1353; DOI: 10.1039/P19880001353 |
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Rhodium-catalysed [2 + 2 + 2]-cycloadditions of acetylenes Ronald Grigg Ronald Scott and Paul Stevenson pg 1357; DOI: 10.1039/P19880001357 |
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Rhodium(I)-catalysed reactions of enynes. Linear coupling vs. cycloaddition Ronald Grigg Ronald Scott and Paul Stevenson pg 1365; DOI: 10.1039/P19880001365 |
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Carotenoids and related compounds. Part 40. Synthesis of trikentriorhodin and other -diketones Akash K. Chopra Gerard P. Moss and Basil C. L. Weedon pg 1371; DOI: 10.1039/P19880001371 |
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Carotenoids and related compounds. Part 41. Structure of mytiloxanthin and synthesis of a cis-isomer Akash K. Chopra Anakshi Khare Gerard P. Moss and Basil C. L. Weedon pg 1383; DOI: 10.1039/P19880001383 |
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Carotenoids and related compounds. Part 42. Structure of isomytiloxanthin Anakshi Khare Gerard P. Moss and Basil C. L. Weedon pg 1389; DOI: 10.1039/P19880001389 |
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Synthesis of 2,3-disubstituted cyclopent-2-en-1-ones from 6-methoxyindanone Christopher J. Moody and Judy Toczek pg 1397; DOI: 10.1039/P19880001397 |
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Synthesis of tetrahydrodicranenone B Christopher J. Moody Stanley M. Roberts and Judy Toczeka pg 1401; DOI: 10.1039/P19880001401 |
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Diels–Alder reactivity of pyrano[3,4-b]indol-3-ones. Part 2. Steric and electronic effects in the addition to alkynes Christopher J. Moody and Pritom Shah pg 1407; DOI: 10.1039/P19880001407 |
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Rhodium carbenoid mediated cyclisations. Part 2. Synthesis of cyclic ethers Julie C. Heslin and Christopher J. Moody pg 1417; DOI: 10.1039/P19880001417 |
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Medicinal plants of southern Africa. Part 2. Synthesis of 1,3-bis-(4-methoxyphenyl)penta-1,4-diene, a stereoisomer of dimethylhinokiresinol, and its 4-monomethoxy analogue Farouk Ameer Siegfried E. Drewes Mark W. Drewes Gregory H. P. Roos and Martin C. Watson pg 1425; DOI: 10.1039/P19880001425 |
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Photoresponsive crown ethers. Part 20. Reversible photocontrol of association–dissociation equilibria between azobis(benzo-18-crown-6) and diammonium cations Seiji Shinkai Tohru Yoshida Osamu Manabe and Yoshio Fuchita pg 1431; DOI: 10.1039/P19880001431 |
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The preparation of 3-benzyl-6-(-methylbenzyl)- and 3,6-bis(-methylbenzyl)-s-tetrazines by alkylation of 3,6-dibenzyl-s-tetrazine and a study of their rearrangements to imidazo[1,2-b]-s-tetrazines in alkali Daniel Hunter and Douglas G. Neilson pg 1439; DOI: 10.1039/P19880001439 |
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The biosynthesis of glaucine in Litsea glutinosa Dewan S. Bhakuni and Sudha Jain pg 1447; DOI: 10.1039/P19880001447 |
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The stereochemistry of a rearrangement and fragmentation reaction of ring D of 13-hydroxygibberellins Isidro G. Collado Braulio M. Fraga James R. Hanson Peter B. Hitchcock and Fernando G. Tellado pg 1451; DOI: 10.1039/P19880001451 |
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The conformation of some site-specific inhibitors of the ring contraction step in gibberellin plant hormone biosynthesis Mark K. Baynham Julia M. Dickinson James R. Hanson Peter B. Hitchcock and Christine L. Willis pg 1455; DOI: 10.1039/P19880001455 |
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Aromatization of 7,17-diacetoxy-4-methyleneandrost-5-ene James R. Hanson and Almaz Truneh pg 1461; DOI: 10.1039/P19880001461 |
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Stereochemistry of hydroboronation and osmylation of 3,5-cycloandrost-6-en-17-one James R. Hanson Peter B. Hitchcock Paul B. Reese and Almaz Truneh pg 1465; DOI: 10.1039/P19880001465 |
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Steroidal allylic and homoallylic rearrangements during halogenation with triphenylphosphine and carbon tetrachloride James R. Hanson Peter B. Hitchcock Paul B. Reese and Almaz Truneh pg 1469; DOI: 10.1039/P19880001469 |
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Stereochemistry of epoxidation of some A-norandrost-5-enes John F. Gordon James R. Hanson Peter B. Hitchcock Andrew G. Jarvis Harry J. Wadsworth and Arnold H. Ratcliffe pg 1473; DOI: 10.1039/P19880001473 |
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Studies in terpenoid biosynthesis. Part 35. Biosynthetic sequences leading to the diterpenoid aphidicolin in Cephalosporium aphidicola Mark J. Ackland John F. Gordon James R. Hanson Boon Leng Yeoh and Arnold H. Ratcliffe pg 1477; DOI: 10.1039/P19880001477 |
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Tetrahydroisoquinolines. Part 4. Enantioselective conversion of (+)-amphetamine into (+)-(1R,3S,4S)- and (–)-(1S,3S,4R)-1,2,3,4-tetramethyl-1,2,3,4-tetrahydroisoquinoline via tricarbonyl(arene)chromium methodology Steven J. Coote Stephen G. Davies and Kevin H. Sutton pg 1481; DOI: 10.1039/P19880001481 |
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Benzopyrans. Part 23. Nitrogen heterocycles fused with or linked to 1-benzopyran from 3-acyl-2-methyl-1-benzopyran-4-one Chandra Kanta Ghosh Chandana Pal Jharna Maiti and Manjusha Sarkar pg 1489; DOI: 10.1039/P19880001489 |
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Structure–reactivity relationships in normal and 19-nor-5,10-seco-steroidal cyclodecenone systems. Part 1. Acid-catalyzed and thermal reactions Ljubinka Lorenc Milica Rajkovi  Aleksandar Milovanovi and Mihailo Lj. Mihailovi pg 1495; DOI: 10.1039/P19880001495 |
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Chemistry of silyl thioketones. Part 4. 2,4,6-Triaryl-2,4,6-tris(trimethylsilyl)-1,3,5-trithianes from silyl thioketones: crystal structure of 2,4,6-triphenyl-2,4,6-tris(trimethylsilyl)-1,3,5-trithiane and stereochemistry of desilylation with fluoride ion Bianca F. Bonini Germans Mazzanti Paolo Zani Gaetano Maccagnani and Elisabetta Foresti pg 1499; DOI: 10.1039/P19880001499 |
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Stereocontrolled synthesis of the brassinolide side-chain: formal synthesis of brassinolide Tetsuji Kametani Masaharu Kigawa Masayoshi Tsubuki and Toshio Honda pg 1503; DOI: 10.1039/P19880001503 |
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1,2,3-Benzotriazine 2-oxides A. J. Boulton Miklós Kiss and J. D. Kalenga Saka pg 1509; DOI: 10.1039/P19880001509 |
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Partial synthesis of 4-epi-trachylobagibberellin A12 Braulio M. Fraga Ricardo Guillermo Jacinto D. Arraez Javier G. Luis and Aurea Perales pg 1513; DOI: 10.1039/P19880001513 |
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On the mechanism of reductive degradation of dithiocarbonates by tributylstannane Mario D. Bachi and Eric Bosch pg 1517; DOI: 10.1039/P19880001517 |
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Synthesis and reaction of optically active morpholinones Choji Kashima and Kazuo Harada pg 1521; DOI: 10.1039/P19880001521 |
The chemistry of terpenes. Part 27. The halogenation of (+)-thujone and of (–)-carvotanacetone, and the stereochemistry and mechanism of formation of  tribromothujone Wesley Cocker Patrick V. R. Shannon and Marion Dowsett pg 1527; DOI: 10.1039/P19880001527 |
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New pseudoanisatin-like sesquiterpene lactones from the bark of Illicium dunnianum Isao Kouno Nobusuke Kawano and Chun-Shu Yang pg 1537; DOI: 10.1039/P19880001537 |
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Synthesis and properties of cyclohepta[fg]naphth[2,3-a]acenaphthylene-5,12-dione (naphth[2,3-h]acepleiadylene-5,12-dione) Josuke Tsunetsugu Shinri Tanaka Seiji Ebine and Kenichi Morinaga pg 1541; DOI: 10.1039/P19880001541 |
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Stereochemistry of cysteinesulphinic acid decarboxylase D. John Aberhart pg 1547; DOI: 10.1039/P19880001547 |
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Synthesis of analogues of 6-bromopenicillanic acid and penicillanic acid S,S-dioxide. Part 1. Synthesis of 3-derivatives of 6-bromo-2,2-dimethylpenam and 2,2-dimethylpenam S,S-dioxide Ernesto G. Mata Eduardo L. Setti Oreste A. Mascaretti Silvans B. Boggio and Oscar A. Roveri pg 1551; DOI: 10.1039/P19880001551 |
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Synthetic studies relevant to biosynthetic research on vitamin B12. Part 6. Synthesis of chlorins by a photochemical approach Alan R. Battersby Christopher J. Dutton Christopher J. R. Fookes and Simon P. D. Turner pg 1557; DOI: 10.1039/P19880001557 |
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Synthetic studies relevant to biosynthetic research on vitamin B12. Part 7. Synthesis of ()-bonellin dimethyl ester Alan R. Battersby Christopher J. Dutton and Christopher J. R. Fookes pg 1569; DOI: 10.1039/P19880001569 |
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Synthetic studies relevant to biosynthetic research on vitamin B12. Part 8. Synthesis of ()-Faktor-I octamethyl ester Alan R. Battersby Simon P. D. Turner Michael H. Block Zhi-Chu Sheng and Steven C. Zimmerman pg 1577; DOI: 10.1039/P19880001577 |
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Reaction of benzonitrile N-(p-nitrophenyl)imide with 5-substituted tetrazoles: a new route to substituted 1,2,4-triazoles via N-hydrazonoyltetrazoles Richard N. Butler and Kevin J. Fitzgerald pg 1587; DOI: 10.1039/P19880001587 |
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Chiral synthesis of 3-[(R)-1-hydroxyethyl]-4-oxoazetidin-2-yl acetate using an asymmetric 1,3-bipolar cycloaddition reaction Tetsuji Kametani Shih-Der Chu and Toshio Honda pg 1593; DOI: 10.1039/P19880001593 |
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The 4-demethylation of lanostenone Katherine Carr Helen M. Saxton and James K. Sutherland pg 1599; DOI: 10.1039/P19880001599 |
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Synthesis of lignans related to the podophyllotoxin series Andrew Pelter Robert S. Ward Martyn C. Pritchard and I. Trevor Kay pg 1603; DOI: 10.1039/P19880001603 |
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A short versatile synthesis of aryltetralin lignans including deoxyisopodophyllotoxin and epi-isopodophyllotoxin Andrew Pelter Robert S. Ward Martyn C. Pritchard and I. Trevor Kay pg 1615; DOI: 10.1039/P19880001615 |
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Synthesis of ()-nitramine and ()-isonitramine William Carruthers and Roger C. Moses pg 1625; DOI: 10.1039/P19880001625 |
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Corrigendum Takayuki Suga Shinji Ohta and Tatsuya Ohmoto pg 1629; DOI: 10.1039/P19880001629 |
Issue 7
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Front cover pg X025; DOI: 10.1039/P198800FX025 |
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Contents pages pg P025; DOI: 10.1039/P198800FP025 |
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Back cover pg X027; DOI: 10.1039/P198800BX027 |
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Preparation of N,O-aminals as synthetic equivalents of H2CNAr and (H2CNHAr)+ ions: neutral- and acid-promoted transformations José Barluenga Ana M. Bayón Pedro Campos Gregorio Asensio Elena Gonzalez-Nuñez and Yolanda Molina pg 1631; DOI: 10.1039/P19880001631 |
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Synthesis of queuine, the base of naturally occurring hypermodified nucleoside (queuosine), and its analogues Hiroshi Akimoto Eiko Imamiya Takenori Hitaka Hiroaki Nomura and Susumu Nishimura pg 1637; DOI: 10.1039/P19880001637 |
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Opioid agonists and antagonists. Peptides containing N-terminal allyl groups and/or a thiomethylene linkage in place of a peptide bond Gianfranco Balboni Severo Salvadori Mauro Marastoni Roberto Tomatis Pier A. Borea and Clementine Bianchi pg 1645; DOI: 10.1039/P19880001645 |
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Boar taint steroid derivatives for immunological studies. Synthesis of 11 -hydroxy-5-androst-16-en-3-one and its hemisuccinate Alan B. Turner and Philip T. van Leersum pg 1653; DOI: 10.1039/P19880001653 |
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Reactions of some 1,3-diaminonucleophiles with azlactones Ahmad M. Tikdari Pradeep K. Tripathy and Arya K. Mukerjee pg 1659; DOI: 10.1039/P19880001659 |
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Photoreactions of indoline-2-thiones with cyanoalkenes Takehiko Nishio Norikazu Okuda and Yoshimori Omote pg 1663; DOI: 10.1039/P19880001663 |
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Samarium(II) di-iodide induced reductive coupling of ,-unsaturated esters with carbonyl compounds leading to a facile synthesis of -lactone Shin-ichi Fukuzawa Akira Nakanishi Tatsuo Fujinami and Shizuyoshi Sakai pg 1669; DOI: 10.1039/P19880001669 |
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Lead(IV) ester and electrochemical oxidations of phenolic compounds: a comparative study Michael J. Begley G. Bryon Gill Gerald Pattenden Alan Stapleton and Richard A. Raphael pg 1677; DOI: 10.1039/P19880001677 |
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Novel alkoxylations of cephalosporins by cerium(IV) salts and by electro-oxidative procedures Gerald Pattenden Alan Stapleton David C. Humber and Stanley M. Roberts pg 1685; DOI: 10.1039/P19880001685 |
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Studies on fungal products. Part 17. Isolation and structures of novel indoloditerpenes, emindoles DA and DB, from Emericella desertorum: X-ray molecular structure of emindole DA acetate Koohei Nozawa Shoichi Nakajima Ken-ichi Kawai and Shun-ichi Udagawa pg 1689; DOI: 10.1039/P19880001689 |
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Syntheses and reactions of optically active alkyltoluene-p-sulphinamides. Part 2. Substitution at sulphur with retention of configuration Stefano Colonna Giulio Germinario Amedea Manfredi and Charles J. M. Stirling pg 1695; DOI: 10.1039/P19880001695 |
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Photosensitized oxidation of furans. Part 13. Trapping reactions of the carbonyl oxides obtained from some 2-methoxy-5-phenylfurans M. Liliana Graziano M. Rosaria Lesce Guido Cimminiello and Rachele Scarpati pg 1699; DOI: 10.1039/P19880001699 |
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Synthesis of 6-hydroxy-1,4-dimethylisoquinoline and of ethyl 7-hydroxy-6-methoxy-1-methylisoquinoline-3-carboxylate Silvio J. Martinet Lesley Larsen Jonathan D. Street and John A. Joule pg 1705; DOI: 10.1039/P19880001705 |
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Dienediolates from unsaturated carboxylic acids: Michael addition of dilithium buta-1,3-diene-1,1-diolate (from crotonic acid) to unsaturated ketones Pablo Ballester Antonio Costa Angel Garcia Raso Antonio Gómez-Solivellas and Ramon Mestres pg 1711; DOI: 10.1039/P19880001711 |
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Biosynthesis of the macrotetrolide antibiotics; the incorporation of carbon-13 and oxygen-18 labelled acetate, propionate, and succinate Doreen M. Ashworth John A. Robinson and David L. Turner pg 1719; DOI: 10.1039/P19880001719 |
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Magnesium- and titanium-induced reductive coupling of carbonyl compounds: efficient syntheses of pinacols and alkenes Alois Fürstner Rene Csuk Christian Rohrer and Hans Weidmann pg 1729; DOI: 10.1039/P19880001729 |
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meso-Reactivity of porphyrins and related compounds. Part 10. Direct fluorination of octaethylporphyrin with caesium fluoroxysulphate Laura E. Andrews Raymond Bonnett Andrei N. Kozyrev and Evan H. Appelman pg 1735; DOI: 10.1039/P19880001735 |
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Cycloaddition of unactivated 2-aza-1,3-dienes with heterocumulenes: a convenient route to the synthesis of 1,3-difunctionalized compounds José Barluenga Francisco J. González Vicente Gotor and Santos Fustero pg 1739; DOI: 10.1039/P19880001739 |
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Organic heterocyclothiazenes. Part 7. Chemistry of 1,3,5,2,4,6-trithiatriazepines Peter J. Dunn Janet L. Morris and Charles W. Rees pg 1745; DOI: 10.1039/P19880001745 |
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Cyclodehydration of non-aromatic diols on AlIII-montmorillonite clay: reactivity and mechanism Dilip Kotkar Satish W. Mahajan Arun K. Mandal and Pushpito K. Ghosh pg 1749; DOI: 10.1039/P19880001749 |
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(+)-(3-Oxocamphorsulphonyl)oxaziridune as a highly stereoselective reagent for the oxidation of sulphides to chiral sulphoxides Gudrun Glahsl and Rudolf Herrmann pg 1753; DOI: 10.1039/P19880001753 |
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Allenes. Part 48. A new general method for the synthesis of dihydro-4H-1,4-thiazines Stephen R. Landor Phyllis D. Landor John Seliki-Muruumu Z. Tanee Fomum and J. Tanyi Mbafor pg 1759; DOI: 10.1039/P19880001759 |
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Studies related to penicillins. Part 24. A novel thiazolidine ring enlargement of penam dioxides G. D. Sriyani Ananda John Steele and Richard J. Stoodley pg 1765; DOI: 10.1039/P19880001765 |
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Asymmetric Diels–Alder reactions. Part 1. Diastereofacial reactivity of (E)-3-trimethylsilyloxybuta-1,3-dienyl 2,3,4,6-tetra-O-acetyl--D-glucopyranoside towards cyclic dienophiles Ramesh C. Gupta Clive M. Raynor Richard J. Stoodley Alexandra M. Z. Slawin and David J. Williams pg 1773; DOI: 10.1039/P19880001773 |
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Efficient 1,4-asymmetric induction utilizing electrostatic interaction between ligand and substrate in the asymmetric hydrogenation of didehydrodipeptides Takamichi Yamagishi Satoru Ikeda Masanobu Yatagai Motowo Yamaguchi and Mitsuhiko Hida pg 1787; DOI: 10.1039/P19880001787 |
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Synthesis of 4-benzoyl-4-methylcyclohexa-2,5-dienone and its benzoyl substituted derivatives: isolated 4-acylcyclohexa-2,5-dienones Lorraine B. Jackson and Anthony J. Waring pg 1791; DOI: 10.1039/P19880001791 |
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Synthesis of single isomers (E or Z) of unsaturated carboxylic acids by the Horner-Wittig reaction Daniel Levin and Stuart Warren pg 1799; DOI: 10.1039/P19880001799 |
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1,3,9,11,12,14-Hexa-azapentacene-2,4,8,10(3H,9H,12H,14H)-tetraones (doubled 5-deazaflavins) with potential for oxido reduction Fumio Yoneda and Masakazu Koga pg 1809; DOI: 10.1039/P19880001809 |
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2,4,5,8,9,11-Hexa-azapentaphene-1,3,10,12(2H,5H,8H,11H)-tetraones (angular 5-deazapteridino-deazaflavins) with strong oxidizing power Fumio Yoneda Masakazu Koga and Yumihiko Yano pg 1813; DOI: 10.1039/P19880001813 |
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Iminophosphorane-mediated annelation of a pyridine or pyrimidine ring into an indole ring: synthesis of -, -carbolines and pyrimido[4,5-b]indole derivatives Pedro Molina and Pilar M. Fresneda pg 1819; DOI: 10.1039/P19880001819 |
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Synthesis of indolin-2-ones (oxindoles) related to mitomycin A Ralph A. Raphael and Paul Ravenscroft pg 1823; DOI: 10.1039/P19880001823 |
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Reactions of 3-bromo-2,3-dihydro- and 2,3-dibromo-4H-1-benzothiopyran-4-one 1,1-dioxides with various amines Shigeru Watanabe Hiroyuki Nakazumi and Teijiro Kitao pg 1829; DOI: 10.1039/P19880001829 |
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A novel, base-induced fragmentation of hantzsch-type 4-aryl-1,4-dihydropyridines Thomas McInally and Alan C. Tinker pg 1837; DOI: 10.1039/P19880001837 |
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Autoxidation of a sterically hindered phenanthrene-4,5-diol and conversion of the products into phenanthrenequinones Lutz M. Engelhardt Frank R. Hewgill Jeffery M. Stewart and Allan H. White pg 1845; DOI: 10.1039/P19880001845 |
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New glucoside conjugates and other cardenolide glycosides from the monarch butterfly reared on Asclepias fruticosa L. H. T. Andrew Cheung Carolyn J. Nelson and Thomas R. Watson pg 1851; DOI: 10.1039/P19880001851 |
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Intermolecular thermal reaction of arylnitrenes with furans Luisa Benati Pier Carlo Montevecchi Maurizio Toselli and Piero Spagnolo pg 1859; DOI: 10.1039/P19880001859 |
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Thermorubin biosynthesis: evidence for the involvement of both salicylic acid and an undecaketide Fabrizio Aragozzini Renato Craveri Elisabetta Maconi Giuliana Severini Ricca and Carlo Scolastico pg 1865; DOI: 10.1039/P19880001865 |
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Sulphur nitride in organic chemistry. Part 17. Preparation of 1,8-diaminocarbazole Kazufumi Takahashi Hisao Eguchi Sohgo Shiwaku Taizo Hatta Eiji Kyoya Tadashi Yonemitsu Shuntaro Mataka and Masashi Tashiro pg 1869; DOI: 10.1039/P19880001869 |
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Isoxazole–oxazole conversion by Beckmann rearrangement Gábor Doleschall and Péter Seres pg 1875; DOI: 10.1039/P19880001875 |
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Homogeneous hydrogenation of tetrasubstituted alkene moieties in prochiral didehydro amino acid derivatives catalysed by iridium complexes Javier A. Cabeza Carlos Cativiela Maria D. Diaz de Villegas and Luis A. Oro pg 1881; DOI: 10.1039/P19880001881 |
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Stable 2-thianaphthalenes: synthesis and reactions with electrophiles Mikio Hori Tadashi Kataoka Horoshi Shimizu Ken'ichi Narita Sachio Ohno Haruo Ogura Hiroaki Takayanagi Yoichi Iitaka and Hirozo Koyama pg 1885; DOI: 10.1039/P19880001885 |
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Cyclization of isothiosemicarbazones. Part 8. Formation and structure of gem-bis(3-alkylthio-1H-1,2,4-triazol-1-yl)alkanes and related compounds Chiji Yamazaki Toshie Takahashi and Kumiko Hata pg 1897; DOI: 10.1039/P19880001897 |
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Selective protection of polyamines: synthesis of model compounds and spermidine derivatives M. Lurdes S. Almeida Leif Grehn and Ulf Ragnarsson pg 1905; DOI: 10.1039/P19880001905 |
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Reactive selenoaldehydes formed from selenenyl derivatives by 1,2-elimination and trapped in situ as cycloadducts with conjugated dienes Gordon W. Kirby and Andrew N. Trethewey pg 1913; DOI: 10.1039/P19880001913 |
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Pyrrolizidine alkaloid analogues. Synthesis of macrocyclic diesters of ()-synthanecine a containing 12- to 16-membered rings Robert H. Barbour and David J. Robins pg 1923; DOI: 10.1039/P19880001923 |
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The aberrant biosynthesis of 2-nitro- and 2-bromo-papaverines Dewan S. Bhakuni and Sudha Jain pg 1929; DOI: 10.1039/P19880001929 |
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Synthesis of novel 2,3-dihydro-8H-thieno[2,3-d]azepines and 1,2,3,4-tetrahydro-1H-3-benzazepines via photolyses of 6-azido-2,3-dihydrobenzo[b]thiophene and 6-azido-1,2,3,4-tetrahydronaphthalene Christopher M. Daly Brian Iddon Hans Suschitzky Ulrich Jordis and Fritz Sauter pg 1933; DOI: 10.1039/P19880001933 |
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o-Nitroaniline derivatives. Part 11. 4- and 7-Amino-1H-benzimidazole 3-oxides Ian W. Harvey Michael D. McFarlane David J. Moody and David M. Smith pg 1939; DOI: 10.1039/P19880001939 |
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Nucleophilic reactions of -aminoalkenenitriles Jim-Min Fang and Han-Ting Chang pg 1945; DOI: 10.1039/P19880001945 |
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Structure elucidation of a glycopeptide antibiotic, OA-7653 Siau-Gek Ang Michael P. Williamson and Dudley H. Williams pg 1949; DOI: 10.1039/P19880001949 |
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Thermal decomposition of some allyl methoxyarenesulphinates Kevin H. Bell pg 1957; DOI: 10.1039/P19880001957 |
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Molecular rearrangement of 3-substituted 4-chloro-4,5-epoxide systems in ring A of steroids John F. Templeton V. P. Sashi Kumar Azza A. M. El-Sheikh Talal Hasan Zeglam and Kirk Marat pg 1961; DOI: 10.1039/P19880001961 |
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2-Isopropylidene-, 2-t-butyl-, and 2-isopropyl-gibberellin A4 and spiro[gibberellin A4-2,1-cyclopropane] Andrew M. Fowles and Jake MacMillan pg 1973; DOI: 10.1039/P19880001973 |
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2-Alkyl gibberellins A1 and A4 Andrew M. Fowles Michael H. Beale David N. M. Jones Jake MacMillan and Christine L. Willis pg 1983; DOI: 10.1039/P19880001983 |
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Reaction of -substituted -bromostyrenes with dicarbonyldicyanonickelate(0) anion in alkaline medium under carbon monoxide Masahiro Miura Nobuhiro Shimoura and Masakatsu Nomura pg 1993; DOI: 10.1039/P19880001993 |
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Use of the nuclear Overhauser effect in the determination of the orientation of aromatic substitution in tricyclic quinoxalinones Babajide I. Alo Anthony G. Avent James R. Hanson and Alexandra E. Ode pg 1997; DOI: 10.1039/P19880001997 |
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Preparation of steroidal 5,6-epoxides and their oxidation by chromium trioxide James R. Hanson and Almaz Truneh pg 2001; DOI: 10.1039/P19880002001 |
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An aromatization reaction of a 13-methyl steroid James R. Hanson and Almaz Truneh pg 2005; DOI: 10.1039/P19880002005 |
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Studies in terpenoid biosynthesis. Part 38. The role of an 16,17-epoxyaphidicolane in the minor biosynthetic pathway leading to aphidicolin Mark J. Ackland John F. Gordon James R. Hanson and Arnold H. Ratcliffe pg 2009; DOI: 10.1039/P19880002009 |
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A mild method for the conversion of 1,3-glycols into unsaturated alcohols Mark J. Ackland John F. Gordon James R. Hanson Boon Leng Yeoh and Arnold H. Ratcliffe pg 2013; DOI: 10.1039/P19880002013 |
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Nitrogen bridgehead compounds. Part 74. Cyclization of 2-(2-pyridylaminomethylene)succinates in ethanolic sodium ethoxide. Part 2. Michael addition of pyridyldihydropyrrolones Lelle Vasvári-Debreczy István Hermecz Benjamin Podányi and Tünde Erös-Takácsy pg 2019; DOI: 10.1039/P19880002019 |
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An investigation of potential [2,3]-sigmatropic rearrangements of pentafluorophenyl-aza-, -thio-, and -methylene-sulphonium ylides Gerald M. Brooke and J. A. K. Jamie Ferguson pg 2023; DOI: 10.1039/P19880002023 |
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Syntheses of 2- and 2-deuterio-testosterones and -androst-4-ene-3,17-diones Herbert L. Holland J. Appa Rao and P. Chinna Chenchaiah pg 2027; DOI: 10.1039/P19880002027 |
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Intramolecular ene reaction of the unsaturated acyloin 3-(but-3-enyl)-2-hydroxy-3-methylcyclohexanone David S. Brown Brian A. Marples and Christopher D. Spilling pg 2033; DOI: 10.1039/P19880002033 |
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Synthesis of the 14- and 16-epimers of bufotalin acetate and 16-deacetylcinobufagin Yoshiaki Kamano George R. Pettit Masuo Inoue Machiko Tozawa Cecil R. Smith and David Weisleder pg 2037; DOI: 10.1039/P19880002037 |
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Mechanistic consideration of P-450 dependent enzymic reactions: studies on oestriol biosynthesis David E. Stevenson J. Neville Wright and Muhammad Akhtar pg 2043; DOI: 10.1039/P19880002043 |
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Formation of oxygen-bridged heterocycles in the hantzsch synthesis with 4-(2-hydroxyphenyl)but-3-en-2-one Jan Sv  tlík Franti ek Ture ek and Vladimír Hanu pg 2053; DOI: 10.1039/P19880002053 |
Issue 8
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Front cover pg X029; DOI: 10.1039/P198800FX029 |
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Contents pages pg P029; DOI: 10.1039/P198800FP029 |
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Back cover pg X031; DOI: 10.1039/P198800BX031 |
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Synthesis of (pivaloyloxy)methyl 6-fluoropenicillanate Eduardo L. Setti and Oreste A. Mascaretti pg 2059; DOI: 10.1039/P19880002059 |
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Palladium(II)-catalysed rearrangements of allylic acetates in the syntheses of methyl (10E,12Z)-9-hydroxyoctadeca-10,12-dienoate (-dimorphecolate) and (2E,4Z)-deca-2,4-dienal Martine M. L. Crilley Bernard T. Golding and Colin Pierpoint pg 2061; DOI: 10.1039/P19880002061 |
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Transition–metal mediated asymmetric synthesis. Part 6. Organometallic approaches to the enantiomer synthesis of tridachione: a role for planar chirality in synthesis design Rikki P. Alexander Christopher Morley and G. Richard Stephenson pg 2069; DOI: 10.1039/P19880002069 |
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Synthesis of enantio- and diastereoiso-merically pure substituted prolines via condensation of glycine with olefins activated by a carbonyl group Yuri N. Beloko Aleksandr G. Bulychev Viacheslav A. Pavlov Eugenia B. Fedorova Vladimir A. Tsyryapkin Vladimir A. Bakhmutov and Vasili M. Belikov pg 2075; DOI: 10.1039/P19880002075 |
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Thionation reactions of diacylketene thioacetals with the Lawesson reagent and analogues Agha Zul-Qarnain Khan and Jan Sandström pg 2085; DOI: 10.1039/P19880002085 |
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Nucleophilic addition to tricarbonyliron complexes of ,-unsaturated ketones and the production of 1,4-diketones Timothy N. Danks Devajyoti Rakshit and Susan E. Thomas pg 2091; DOI: 10.1039/P19880002091 |
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New alkoxylated dibenzo[1,4]dichalcogenines as donors for low-dimensional materials: electrochemistry and cation-radical salts Lars Engman Jonas Hellberg Christina Ishag and Svante Söderholm pg 2095; DOI: 10.1039/P19880002095 |
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Synthesis of oligosaccharides corresponding to the antigenic determinants of the -haemolytic Streptococci Group A. Part 1. Overall strategy and synthesis of a linear trisaccharide Kerry B. Reimer and B. Mario Pinto pg 2103; DOI: 10.1039/P19880002103 |
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The pyridylseleno group in organic synthesis. Part 5. Amidoseleniation of alkenes Akio Toshimitsu Gen Hayashi Keiji Terao and Sakae Uemura pg 2113; DOI: 10.1039/P19880002113 |
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Mechanistic studies on lysine 2,3-aminomutase: carbon-13—deuterium crossover experiments D. John Aberhart and Jacques-Alain Cotting pg 2119; DOI: 10.1039/P19880002119 |
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Studies of precursor-directed biosynthesis with Streptomyces sp. Part 1. Isolation of manumycin analogues by feeding of aminobenzoic acids as C7N starter units Ralf Thiericke and Axel Zeeck pg 2123; DOI: 10.1039/P19880002123 |
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Amino acids and peptides. Part 19. Synthesis of -1- and -2-adamantyl aspartates and their evaluation for peptide synthesis Yoshio Okada and Shin Iguchi pg 2129; DOI: 10.1039/P19880002129 |
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Alkylation of nitrocyanamide. A new synthesis of isocyanates Joseph H. Boyer Thanikavelu Manimaran and Lionel T. Wolford pg 2137; DOI: 10.1039/P19880002137 |
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Reaction of benzyne with 1,2,5-thiadiazoles and 2,1-benzisothiazoles Martin R. Bryce Trevor A. Dransfield Kamal A. Kandeel and John M. Vernon pg 2141; DOI: 10.1039/P19880002141 |
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Preparation and X-ray crystal and molecular structure of 6-bromopyrrolizin-3-one Alexander J. Blake Hamish McNab and Roderick Morrison pg 2145; DOI: 10.1039/P19880002145 |
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Benzylic azide functionalization of tautomeric o-acyl-benzoic acid, -benzamide, and -nicotinic acid derivatives, and thermal decomposition of the derived azides Hisato Takeuchi and Shoji Eguchi pg 2149; DOI: 10.1039/P19880002149 |
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Studies on fungal products. Part 19. Isolation and structure of a novel indoloditerpene, emindole SA, from Emericella striata Koohei Nozawa Mari Yuyama Shoichi Nakajima Ken-ichi Kawai and Shun-ichi Udagawa pg 2155; DOI: 10.1039/P19880002155 |
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Synthesis of 15-hydroxy-24-oxocholesterol and 15,29-dihydroxy-7-oxofucosterol Dashan Liu Louise M. Stuhmiller and Trevor C. McMorris pg 2161; DOI: 10.1039/P19880002161 |
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Ring contraction of 1,2,4-benzoxadiazines to benzoxazoles Thomas L. Gilchrist C. John Harris Frank D. King Michael E. Peek and Charles W. Rees pg 2169; DOI: 10.1039/P19880002169 |
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Leurosinone: a new binary indole alkaloid from Catharanthus roseus pg 2175; DOI: 10.1039/P19880002175 |
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Stereoselective C-4 functionalisation of flavan-3-ols. The significance of conformational mobility of the flavan heterocycle in stereoselectivity at the benzylic carbon Jacobus A. Steenkamp Johannes C. S. Malan and Daneel Ferreira pg 2179; DOI: 10.1039/P19880002179 |
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Synthesis of enamides Roger Brettle and Alan J. Mosedale pg 2185; DOI: 10.1039/P19880002185 |
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Reaction of oxophosphorane-sulphenyl and -selenenyl chlorides with dialkyl trimethylsilyl phosphites. Novel synthesis of compounds containing a sulphur or selenium bridge between two phosphoryl centres Aleksandra Skowro ska Roman Dembiski Rafal Kamiski and Jan Michalski pg 2197; DOI: 10.1039/P19880002197 |
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A new synthesis of -lactams via photochemical -hydrogen abstraction of monothioimides Masami Sakamoto Shoji Watanabe Tsutomu Fujita Masakazu Tohnishi Hiromu Aoyama and Yoshimori Omote pg 2203; DOI: 10.1039/P19880002203 |
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Spectrometric and chemical studies of 5-acyl- and 5-nitroso-2-(N,N-disubstituted amino)thiazoles Timothy N. Birkinshaw G. Denis Meakins and Simon J. Plackett pg 2209; DOI: 10.1039/P19880002209 |
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The mechanism of two reactions leading to isomeric 2-(N,N-disubstituted amino)thiazol-5-yl ketones Katherine Challacombe Susan E. Leach Simon J. Plackett and G. Denis Meakins pg 2213; DOI: 10.1039/P19880002213 |
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Photocyclisation of enamides. Part 27. Total syntheses of ()-yohimbine, ()-alloyohimbine, and ()-19,20-didehydroyohimbines Takeaki Naito Yumiko Hirata Okiko Miyata and Ichiya Ninomiya pg 2219; DOI: 10.1039/P19880002219 |
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Nucleosides. Part 5. Isolation and characterization of the stable cyclic adducts, (5R,6S)- and (5S,6S)-bromo-O6,5-cyclo-5,6-dihydrouridines in the bromination of 2,3-O-isopropylideneuridine with N-bromosuccinimide Kosaku Hirota Tetsuo Tomishi Magoichi Sako and Yoshifumi Maki pg 2227; DOI: 10.1039/P19880002227 |
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Nucleosides. Part 6. New chemical modification of the ribosyl moiety in uridines; synthesis of 2,2-anhydro-1-[5-deoxy-5-(substituted thio)--D-arabinofuranosyl]uracil derivatives and their conversion into 3,5-epithiopyrimidine nucleosides Kosaku Hirota Yukio Kitade Tetsuo Tomishi Yoshifumi Maki and Erik De Clercq pg 2233; DOI: 10.1039/P19880002233 |
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Chemistry of bacterial endotoxins. Part 4. Synthesis of anomeric 2-deoxy-2[(3R)-3-hydroxytetradecanamido]-D-glucopyranosyl phosphate and pyrophosphate derivatives related to Lipid A François Trigalo Daniel Charon and Ladislas Szabó pg 2243; DOI: 10.1039/P19880002243 |
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Cycloaddition of 2,3,4,5-tetrahydropyridine N-oxide to isobutyl vinyl ether and allyl alcohol; methyl 2- formylmethylpiperidine-1-carboxylate William Carruthers and Roger C. Moses pg 2251; DOI: 10.1039/P19880002251 |
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Palladium-catalysed spirocyclisation of 3-acetoxy-1-(4-aminoalkyl)cyclohexenes William Carruthers and Roger C. Moses pg 2255; DOI: 10.1039/P19880002255 |
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Studies related to penicillins. Part 25. Synthesis of N-phenylacetyl and N-triphenylmethyl derivatives of 6-aminopenam 1-oxides Arun C. Kaura Christopher D. Maycock Richard J. Stoodley Brian Beagley and Robin G. Pritchard pg 2259; DOI: 10.1039/P19880002259 |
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Reactivities of heteroaromatic cations containing a Group VIB element in nucleophilic reactions. Reactions of 9-phenyl-xanthylium, -thioxanthylium, and -selenoxanthylium salts with amines, sodium phenolate, and sodium benzenethiolate Mikio Hori Tadashi Kataoka Hiroshi Shimizu Chen Fu Hsu Yukio Hasegawa and Noriko Eyama pg 2271; DOI: 10.1039/P19880002271 |
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Thermolysis and photolysis of 1-anilino-2-methyl-4,6-diphenylpyridinium tetrafluoroborate in arene–trifluoroacetic acid mixtures: a novel route to singlet and triplet phenylnitrenium ions Hiroshi Takeuchi and Kikuhiko Koyama pg 2277; DOI: 10.1039/P19880002277 |
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Biosynthesis of streptothricin F. Part 6. Formation and intermediacy of D-glucosamine in Streptomyces L-1689-23 Venkatapuram A. Palaniswamy and Steven J. Gould pg 2283; DOI: 10.1039/P19880002283 |
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13C chemical shift assignments in cyclo-octene, cyclo-octanone, and cyclo-oct-2-enol from the spectra of monodeuterioisotopomers Gordon Read and Janet Shaw pg 2287; DOI: 10.1039/P19880002287 |
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Synthesis of the 5,6-dihydro-2-pyrone moiety of (+)-anamarin Frédéric Gillard Denis Heissler and Jean-Jacques Riehl pg 2291; DOI: 10.1039/P19880002291 |
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Stereo- and regio-control of electrophilic additions to cyclohexene systems by neighbouring groups: participation of allylic and homoallylic ester groups in hypobromous acid addition to some 5-unsaturated cholestane derivatives Pavel Ko ovský Ivo Starý Jaroslav Zajíek Frantiek Tureek and So a Vaíková pg 2297; DOI: 10.1039/P19880002297 |
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An approach to (8,3)- and (8,57,3)-neolignans Simon V. Mortlock Joanna K. Seckington and Eric J. Thomas pg 2305; DOI: 10.1039/P19880002305 |
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Synthesis of nucleosides using ketene dithioacetals Masataka Yokoyama Katsushi Kumata Naoyuki Yamada Hidehiko Noro and Yuka Sudo pg 2309; DOI: 10.1039/P19880002309 |
Chemistry of ketene acetals. Part 9. A simple one-pot synthesis of 4-hydroxy- -lactones and 5,6-dihydro-2-pyrones from 1,1-dimethoxypropene and -oxy aldehydesRob G. Hofstraat Jos Lange Hans W. Scheeren and Rutger J. F. Nivard pg 2315; DOI: 10.1039/P19880002315 |
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Synthesis of an alberta oil sand bitumen C20 tricyclic carboxylic acid bearing a novel diterpenoid skeleton Teodoro S. Kaufman Manuel Gonzalez-Sierra and Edmundo A. Ruveda pg 2323; DOI: 10.1039/P19880002323 |
Reactivity and chemoselectivity of primary Z--enamino- 5-phosphazenes towards electrophilesJosé Barluenga Fernando López Francisco Palacios Félix H. Cano and Maria de la Concepción Foces-Foces pg 2329; DOI: 10.1039/P19880002329 |
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Epoxidation with pyridine–trifluoroacetic anhydride–molecular oxygen and its mechanistic aspects Takashi Harayama Osamu Sakurai Hideto Fukushi Yasuhiro Tezuka and Fumio Yoneda pg 2335; DOI: 10.1039/P19880002335 |
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The chemistry of benzotriazole. Part 8. A novel two-step procedure for the N-alkylation of amides Alan R. Katritzky and Malgorzata Drewniak pg 2339; DOI: 10.1039/P19880002339 |
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Synthesis of -lactam analogues of carbapenems with substituted-thio groups at the C-3 position Shohei Hashiguchi Hideaki Natsugari and Michihiko Ochiai pg 2345; DOI: 10.1039/P19880002345 |
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Synthesis of putative precursors of ecdysone. Part 3. Synthesis of 3, 14, 25-trihydroxy-5-cholest-7-en-6-one Thierry Haag Bang Luu and Charles Hetru pg 2353; DOI: 10.1039/P19880002353 |
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Polarized ketene dithioacetals. Part 65. Studies on additions of 2-aroyl-3-cyano-1,1-bis(methylthio)propenide anions to hetero-multiple bonds Laitonjam W. Singh Hiriyakkanavar Ila and Hiriyakkanavar Junjappa pg 2365; DOI: 10.1039/P19880002365 |
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Stereoselective condensation of bis-p-tolylthiomethane with lactic acid derivatives through an acylation–reduction strategy: synthesis of protected 4-deoxy-L-threose and 4-deoxy-L-erythrose Giuseppe Guanti Luca Banfi Alberto Guaragna and Enrica Narisano pg 2369; DOI: 10.1039/P19880002369 |
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Polymerisation of indole. Part 2. A new indole trimer Hisashi Ishii Keiko Murakami Eri Sakurada (née Kawanabe) Katsuhiro Hosoya and Yasuoki Murakami pg 2377; DOI: 10.1039/P19880002377 |
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Polymerisation of indole. Part 3. Two indolylquinolines, an indole tetramer, and the dihydro derivative of the indole dimer Hisashi Ishii Eni Sakurada (née Kawanabe) Keiko Murakami Shigehiro Takase and Hirokazu Tanaka pg 2387; DOI: 10.1039/P19880002387 |
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Unusual stereoselection in the reaction of dianions derived from 1-phenylsulphonylalkan-2-ols with electrophilic reagents Rikuhei Tanikaga Ken Hosoya and Aritsune Kaji pg 2397; DOI: 10.1039/P19880002397 |
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Penasterol, a novel antileukemic sterol from the okinawan marine sponge Penares sp. Jie-fei Cheng Jun'ichi Kobayashi Hideshi Nakamura Yasushi Ohizumi Yoshimasa Hirata and Takuma Sasaki pg 2403; DOI: 10.1039/P19880002403 |
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Biosynthesis of sitosterol, cycloartenol, and 24-methylenecycloartanol in tissue cultures of higher plants and of ergosterol in yeast from [1,2-13C2]- and [2-13C2H3]-acetate and [5-13C2H2]MVA Shujiro Seo Atsuko Uomori Yohko Yoshimura Ken'ichi Takeda Haruo Seto Yutaka Ebizuka Hiroshi Noguchi and Ushio Sankawa pg 2407; DOI: 10.1039/P19880002407 |
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The chemistry of organolead(IV) tricarboxylates. Synthesis and electrophilic heteroarylation reactions of 2- and 3-thienyl-, and 2- and 3-furyl-lead tricarboxylates John T. Pinhey and Eric G. Roche pg 2415; DOI: 10.1039/P19880002415 |
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Ready oxidation of alcohols to carbonyl compounds by sodium bromite in methylene dichloride in the presence of aluminium oxide Takashi Morimoto Masao Hirano Yumiko Aikawa and Xiumin Zhang pg 2423; DOI: 10.1039/P19880002423 |
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The synthesis of desertorin C, a bicoumarin from the fungus Emericella desertorum Mark A. Rizzacasa and Melvyn V. Sargent pg 2425; DOI: 10.1039/P19880002425 |
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Total synthesis of aaptamine of potent -blocking activity via thermal cyclization of 1-azahexatriene systems Satoshi Hibino Eiichi Sugino Tominari Choshi and Kohichi Sato pg 2429; DOI: 10.1039/P19880002429 |
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A novel synthesis of cyclobutane monoterpenes, ()-grandisol and ()-lineatin Tetsuji Kametani Tetsuya Toya Koji Ueda Masayoshi Tsubuki and Toshio Honda pg 2433; DOI: 10.1039/P19880002433 |
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Novel syntheses of naphthoquinone methide near-infrared dyes Yuji Kubo Fujio Mori Keiko Komatsu and Katsuhira Yoshida pg 2439; DOI: 10.1039/P19880002439 |
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N.m.r. Spectra of porphyrins. Part 35. An examination of the proposed models of the chlorophyll a dimer Raymond J. Abraham Dane A. Goff and Kevin M. Smith pg 2443; DOI: 10.1039/P19880002443 |
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Octa-alkoxy phthalocyanine and naphthalocyanine derivatives: dyes with Q-band absorption in the far red or near infrared Michael J. Cook Adrian J. Dunn Steven D. Howe Andrew J. Thomson and Kenneth J. Harrison pg 2453; DOI: 10.1039/P19880002453 |
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Synthesis and acetylation of naphthols as precursors to naturally derived naphthoquinones; crystal structure of the aphin-related 7-O-methyl quinone A Robin G. F. Giles Ivan R. Green Margaret L. Niven and Selwyn C. Yorke pg 2459; DOI: 10.1039/P19880002459 |
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Syntheses of the aphid pigment derivatives quinone A, quinone A, and deoxyquinone A as racemates John F. Elsworth Robin G. F. Giles Ivan R. Green Jurgen E. Ramdohr and Selwyn C. Yorke pg 2469; DOI: 10.1039/P19880002469 |
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The ansamycins: synthesis of the naphthoquinonoid nucleus of rifamycin W; crystal structure verification of a key naphthalenic intermediate Charles B. de Koning Robin G. F. Giles Lorraine S. Knight Margaret L. Niven and Selwyn C. Yorke pg 2477; DOI: 10.1039/P19880002477 |
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A formal total synthesis of ()-herbertene Ajoy K. Banerjee Carmen A. Peña-Matheud and María C. de Carrasco pg 2485; DOI: 10.1039/P19880002485 |
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Formal synthesis of the antitumour antibiotic CC-1065 Richard E. Bolton Christopher J. Moody Martin Pass Charles W. Rees and Gabriel Tojo pg 2491; DOI: 10.1039/P19880002491 |
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2,3,7,8-Tetra-azatetracyclo[7.3.1.0.0]tridecanes and 2,4,6,8-tetra(alkylamino)bicyclo[3.3.1]nonanes John M. Mellor Ranjith Pathirana and Neil M. Smith pg 2501; DOI: 10.1039/P19880002501 |
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Regioselective synthesis of hydroxy sulphides via trifluoroacetoxysulphenylation of derivatives of allylic alcohols Zakaria K. M. Abd El Samii Mohamed I. Al Ashmawy and John M. Mellor pg 2509; DOI: 10.1039/P19880002509 |
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New routes to heterocycles via sulphenylation of unsaturated amides Zakaria K. M. Abd El Samii Mohamed I. Al Ashmawy and John M. Mellor pg 2517; DOI: 10.1039/P19880002517 |
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Trifluoroacetoxysulphenylation of unsaturated nitriles and transformation of the adducts into lactones Zakaria K. M. Abd El Samii Mohamed I. Al Ashmawy and John M. Mellor pg 2523; DOI: 10.1039/P19880002523 |
Issue 9
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Front cover pg X033; DOI: 10.1039/P198800FX033 |
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Contents pages pg P035; DOI: 10.1039/P198800FP035 |
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Back cover pg X035; DOI: 10.1039/P198800BX035 |
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Macroheterocycles. Part 42. A facile synthesis of dihydroxy cryptands and their dehydroxylation Nikolay G. Lukyanenko and Anatoly S. Reder pg 2533; DOI: 10.1039/P19880002533 |
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Sclerophytins A and B. Isolation and structures of novel cytotoxic diterpenes from the marine coral Sclerophytum capitalis Perveen Sharma and Maktoob Alam pg 2537; DOI: 10.1039/P19880002537 |
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Purines, pyrimidines, and imidazoles. Part 64. Alkylation and acylation of some aminoimidazoles related to intermediates in purine nucleotide de novo and thiamine biosynthesis Grahame Mackenzie Hilary A. Wilson Gordon Shaw and David Ewing pg 2541; DOI: 10.1039/P19880002541 |
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Reaction of acetyl hypofluorite with pyrimidines. Part 3. Synthesis, stereochemistry, and properties of 5-fluoro-5,6-dihydropyrimidine nucleosides Gerard W. M. Visser Renella E. Herder Paul Noordhuis Oene Zwaagstra Jacobus D. M. Herscheid and Frans J. J. de Kanter pg 2547; DOI: 10.1039/P19880002547 |
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Stereo-structures of reaction products of thymidine epoxides with amines and L-amino acid ethyl esters Takashi Harayama Reiko Yanada Mihoko Tanaka Tooru Taga Katsunosuke Machida Fumio Yoneda and Jean Cadet pg 2555; DOI: 10.1039/P19880002555 |
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Amberlyst 15, a superior, mild, and selective catalyst for carbonyl regeneration from nitrogeneous derivatives Roberto Ballini and Marino Petrini pg 2563; DOI: 10.1039/P19880002563 |
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Oligomeric flavanoids. Part 2. The first profisetinidins with dihydroflavonol constituent units Johannes C. S. Malan Desmond A. Young Jacobus A. Steenkamp and Daneel Ferreira pg 2567; DOI: 10.1039/P19880002567 |
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Lignans and related phenols. Part 18. The synthesis of quinones from podophyllotoxin and its analogues David C. Ayres and Timothy J. Ritchie pg 2573; DOI: 10.1039/P19880002573 |
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Preparation and chemical behaviour of exo-methylene compounds: isoelectronic compounds of 5-methylenecyclohexa-1,3-diene Akira Sugimoto Junzo Yamano Masahiro Yasueda and Shigeo Yoneda pg 2579; DOI: 10.1039/P19880002579 |
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Synthetic studies on bicyclomycin and its analogues. Part 1. Synthesis of substituted 2-oxa-8,10-diazabicyclo[4.2.2]decanes Ian M. Dawson Julian A. Gregory Richard B. Herbert and Peter G. Sammes pg 2585; DOI: 10.1039/P19880002585 |
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Synthesis of chrysenes and other a-fused phenanthrenes by a palladium(0) coupling—electrocyclic ring closure sequence Thomas L. Gilchrist and Richard J. Summersell pg 2595; DOI: 10.1039/P19880002595 |
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Synthesis of aromatic steroids by palladium(0) coupling and electrocyclic ring closure Thomas L. Gilchrist and Richard J. Summersell pg 2603; DOI: 10.1039/P19880002603 |
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Isolation and structures of indoloditerpenes, possible biosynthetic intermediates to the tremorgenic mycotoxin, paxilline, from Emericella striata Koohei Nozawa Shoichi Nakajima Ken-ichi Kawai and Shun-ichi Udagawa pg 2607; DOI: 10.1039/P19880002607 |
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Isolation and structures of novel fungal depsidones, emeguisins A, B, and C, from Emericella unguis Nobuo Kawahara Koohei Nozawa Shoichi Nakajima Ken-ichi Kawai and Mikio Yamazaki pg 2611; DOI: 10.1039/P19880002611 |
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The reaction of ortho-substituted aromatic azides with boron trichloride or trifluoride Piero Spagnolo and Paolo Zanirato pg 2615; DOI: 10.1039/P19880002615 |
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Identification of the absolute stereochemistry of D- and L-digitoxose using a chiral high-pressure liquid chromatography column Sachiko Tsukamoto Koji Hayashi and Kô Kaneko pg 2621; DOI: 10.1039/P19880002621 |
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Studies on the constituents of Asclepiadaceae plants. Part 67. Further studies on glycosides with a novel sugar chain containing a pair of optically isomeric sugars, D- and L-cymarose, from Cynanchum africanum Sachiko Tsukamoto Koji Hayashi Kô Kaneko Hiroshi Mitsuhashi Friedrich O. Snyckers and Theunis G. Fourie pg 2625; DOI: 10.1039/P19880002625 |
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Synthesis of erivanin and 1-epierivanin from 1-()-santonin Ravi S. Harapanhalli pg 2633; DOI: 10.1039/P19880002633 |
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Alkylation studies of 5-exo-methylene substituted isoxazolidines Albert Padwa Stephen P. Carter Ugo Chiacchio Donald N. Kline and John Perumattam pg 2639; DOI: 10.1039/P19880002639 |
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Endoannular interactions in cysteine-containing cyclotripeptides: one-step synthesis and crystal structure of a tetracyclic aza-cyclol Giancarlo Zanotti Francesco Pinnen Gino Lucente Silvio Cerrini and Enrico Gavuzzo pg 2647; DOI: 10.1039/P19880002647 |
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Photochemistry of 5-methylpyrimidin-4-ones in acetic acid solution: thermal rearrangements of Dewar pyrimidinones and 4-acetoxyazetidin-2-ones Tamiko Takahashi Shun-ichi Hirokami Masanori Nagata and Takao Yamazaki pg 2653; DOI: 10.1039/P19880002653 |
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A stereocontrolled approach to electrophilic epoxides Otto Meth-Cohn Clive Moore and Heinrich C. Taljaard pg 2663; DOI: 10.1039/P19880002663 |
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Synthetic studies on antibiotic validamycins. Part 12. Total synthesis of (+)-validamycin B and (+)-validoxylamine B Seiichiro Ogawa Yasunobu Miyamoto and Taisuke Nose pg 2675; DOI: 10.1039/P19880002675 |
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Stereochemical features of the anomerizations in the 5,6-dihydrothymine nucleoside series Jasenka Matuli -Adami Maja Pavela-Vrani and Vinko  kari pg 2681; DOI: 10.1039/P19880002681 |
Issue 10
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Front cover pg X037; DOI: 10.1039/P198800FX037 |
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Contents pages pg P039; DOI: 10.1039/P198800FP039 |
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Back cover pg X039; DOI: 10.1039/P198800BX039 |
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Oxidations of enone systems in steroids by oxidizers with reversible redox potential Jan Jasiczak pg 2687; DOI: 10.1039/P19880002687 |
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XY–ZH systems as potential 1,3-dipoles. Part 11. Stereochemistry of 1,3-dipoles generated by the decarboxylative route to azomethine ylides Ronald Grigg Sivagnanasundram Surendrakumar Sunit Thianpatanagul and David Vipond pg 2693; DOI: 10.1039/P19880002693 |
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XY–ZH systems as potential 1,3-dipoles. Part 12. Mechanism of formation of azomethine ylides via the decarboxylative route from -amino acids Ronald Grigg Jonathan Idle Peter McMeekin Sivagnanasundram Surendrakumar and David Vipond pg 2703; DOI: 10.1039/P19880002703 |
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Enantioselectivity of the microsomal epoxide hydrolase: hydrolysis of ()-cis-3-bromo-1,2-epoxycyclohexane Giuseppe Bellucci Maria Ferretti Annalisa Lippi and Franco Marioni pg 2715; DOI: 10.1039/P19880002715 |
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Rearrangements of aromatic carbonyl arylhydrazones of benzene, naphthalene, and azulene Tiziana Benincori Silvia Bradamante Pagani Raffaello Fusco and Franco Sannicolò pg 2721; DOI: 10.1039/P19880002721 |
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N.m.r. and conformational studies of the methyl glycosides of some 1,2- and 1,3-linked disaccharides Per-Erik Jansson Lennart Kenne and Elke Schweda pg 2729; DOI: 10.1039/P19880002729 |
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A stereochemical study of the dissociative substitution reactions of N-(S)--phenylethyl-P-t-butylphosphonamidic chloride with t-butylamine and isopropylamine Sally Freeman and Martin J. P. Harger pg 2737; DOI: 10.1039/P19880002737 |
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Synthesis of an aromatic hydrocarbon diol epoxide–cytosine adduct, 5-O-(9-phenylxanthen-9-yl)-N4-[()-1,2,3-triacetoxy-1,2,3,4-tetrahydro-4-naphthyl]-2-deoxycytidine, suitable for incorporation into synthetic oligodeoxyribonucleotides Clive A. Smith Andrea E. Harper and Maurice M. Coombs pg 2745; DOI: 10.1039/P19880002745 |
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Preparation and properties of novel sulphur heterocycles from the reaction of 4,5-disubstituted 2-lithio-1,3-dithioles with carbon disulphide and X-ray crystallographic structure of 2-(4,5-dimethyl-1,3-dithiolylidene)-5,6-dimethyl-2,3-dihydro-1,4-dithiine-3-thione Alec Moradpour Shmuel Bittner Joel Bernstein and Jagarlapudi A. R. P. Sarma pg 2751; DOI: 10.1039/P19880002751 |
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Analogues of the antiviral acyclonucleoside 9-(4-hydroxy-3-hydroxymethylbutyl)guanine. Part 1. Substitutions on C-2 of the acyclic N-9 substituent Michael R. Harnden Ann Parkin and Paul G. Wyatt pg 2757; DOI: 10.1039/P19880002757 |
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Analogues of the antiviral acyclonucleoside 9-(4-hydroxy-3-hydroxymethylbutyl)guanine. Part 2. Substitutions on C-1 and C-3 of the acyclic N-9 substituent Stuart Bailey and Michael R. Harnden pg 2767; DOI: 10.1039/P19880002767 |
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Analogues of the antiviral acyclonucleoside 9-(4-hydroxy-3-hydroxymethylbutyl)guanine. Part 3. Modification of a 3-hydroxymethyl group Michael R. Harnden and Richard L. Jarvest pg 2777; DOI: 10.1039/P19880002777 |
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Synthesis of 2-substituted 4-pyridylpropionates. Part 1. Claisen condensation approach Brian M. Adger Robin Bannister Norman J. Lewis and Clare O'Farrell pg 2785; DOI: 10.1039/P19880002785 |
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Synthesis of 2-substituted 4-pyridylpropionates. Part 2. Alkylation approach Brian M. Adger Peter Ayrey Robin Bannister Michael A. Forth Yousef Hajikarimian Norman J. Lewis Clare O'Farrell Nicholas Owens and Amin Shamji pg 2791; DOI: 10.1039/P19880002791 |
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Unsaturated carboxylic acid polyenolates. Lithium trienolate of sorbic acid as a d6 synthon: addition to ketones and unsaturated ketones Pablo Ballester Antonio Costa Angel Garczía-Raso and Ramon Mestres pg 2797; DOI: 10.1039/P19880002797 |
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N-halogeno compounds. Part 9. N-Fluoroquinuclidinium fluoride—a new electrophilic fluorinating agent Ronald Eric Banks Richard Arthur Du Boisson William David Morton and Efthimios Tsiliopoulos pg 2805; DOI: 10.1039/P19880002805 |
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Studies related to penicillins. Part 26. Conversion of potassium benzylpenicillinate into 1-substituted derivatives of 3-phenylacetamidoazetidine-2,4-dione Arun C. Kaura and Richard J. Stoodley pg 2813; DOI: 10.1039/P19880002813 |
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Synthesis of the major urinary metabolite of prostaglandin D2 Chandra Prakash Samir Saleh L. Jackson Roberts II Ian A. Blair and Douglass F. Taber pg 2821; DOI: 10.1039/P19880002821 |
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Stereoselectivity during fungal sulphoxidations of 1,3-dithiolanes Barbara J. Auret Derek R. Boyd Robert Dunlop and Alex F. Drake pg 2827; DOI: 10.1039/P19880002827 |
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Homochiral fluoro-organic compounds. Microbial reduction of 1-fluoro-3-(p-tolylsulphonyl)propan-2-one and of 1-fluoro-3-(p-tolylsulphenyl)propan-2-one Rosanna Bernardi Pierfrancesco Bravo Rosanna Cardillo Dario Ghiringhelli and Giuseppe Resnati pg 2831; DOI: 10.1039/P19880002831 |
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Asymmetric synthesis of trans-benzoperhydroindan: asymmetric induction in intramolecular Diels–Alder reactions of o-quinodimethanes Hideo Nemoto Mitsuo Nagai Kouichi Kohzuki Keiichiro Fukumoto and Tetsuji Kametani pg 2835; DOI: 10.1039/P19880002835 |
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Reactivity of phenyliodonium bis(arylsulphonyl)methylides towards alkenes and alkynes: crystal structure of 9-phenylsulphonyl-1,2,3,4,4a,9a-hexahydro-1,4- methanofluorene Lazaros Hatjiarapoglou Anastassios Varvoglis Nathaniel W. Alcock and Graham A. Pike pg 2839; DOI: 10.1039/P19880002839 |
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The -vinylation of -dicarbonyl compounds by alk-1-enyl-lead triacetates Mark G. Moloney and John T. Pinhey pg 2847; DOI: 10.1039/P19880002847 |
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-Hydroxy ketones from the iodine-catalysed reaction of -bromo ketone with aldehydes mediated by trialkylstibine Yao-Zeng Huang Chen Chen and Yanchang Shen pg 2855; DOI: 10.1039/P19880002855 |
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Aldol reaction of reducing sugars. Convenient stereoselective synthesis of ribofuranosylacetone and chiral dienones Ana Calvo-Mateo María-José Camarasa Angel Díaz-Ortíz Federico G. De las Heras and Antonio Alemanya pg 2861; DOI: 10.1039/P19880002861 |
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Direct incorporation of a 6(7)-formamido group into penicillin and cephalosporin sulphides and sulphoxides Clive L. Branch Michael J. Pearson and Terence C. Smale pg 2865; DOI: 10.1039/P19880002865 |
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Thermal interconversion and cyclisation reactions of 2-(arylthio)benzyl radicals and 2-(benzyl)thiophenoxyl radicals J. I. G. Cadogan H. Susan Hutchison and Hamish McNab pg 2875; DOI: 10.1039/P19880002875 |
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A new synthesis of 1-arylpiperidin-4-ols Colin B. Reese and Elizabeth A. Thompson pg 2881; DOI: 10.1039/P19880002881 |
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Peptide synthesis. Part 12. 3,4-Dihydro-4-oxo-1,2,3-benzotriazin-3-yl esters of fluorenylmethoxycarbonyl amino acids as self-indicating reagents for solid phase peptide synthesis Eric Atherton Jill L. Holder Morten Meldal Robert C. Sheppard and Robert M. Valerio pg 2887; DOI: 10.1039/P19880002887 |
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Peptide synthesis. Part 13. Feedback control in solid phase synthesis. Use of fluorenylmethoxycarbonyl amino acid 3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-yl esters in a fully automated system Linda R. Cameron Jill L. Holder Morten Meldal and Robert C. Sheppard pg 2895; DOI: 10.1039/P19880002895 |
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Corrigendum Saul J. B. Tendler Michael D. Threadgill and Michael J. Tisdale pg 2903; DOI: 10.1039/P19880002903 |
Issue 11
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Front cover pg X041; DOI: 10.1039/P198800FX041 |
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Contents pages pg P043; DOI: 10.1039/P198800FP043 |
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Back cover pg X043; DOI: 10.1039/P198800BX043 |
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Conjugate addition with organometallics and nitration of nitroxide (aminoxyl) free radicals. Synthesis of potentially useful cross-linking spin label reagents Kálmán Hideg H. Olga Hankovszky H. Anna Halász and Pál Sohár pg 2905; DOI: 10.1039/P19880002905 |
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Valence isomer interconversion of norbornadienes and quadricyclanes having an acyl group Ken-ichi Hirao Asami Yamashita Akira Ando Tatsuo Hamada and Osamu Yonemitsu pg 2913; DOI: 10.1039/P19880002913 |
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The reactions of hydrazones and related compounds with strong bases. Part 4. 4,5-Diaryl-1,2,3-triazoles from aromatic aldehyde azines and from the reaction of arenecarbonitriles with aryldiazomethanes Michael F. Grundon and Ejaz A. Khan pg 2917; DOI: 10.1039/P19880002917 |
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Synthesis of stable 3,6-epidioxypyrazin-2-ones and -oxo imides by photo-oxygenation of pyrazin-2-ones with singlet oxygen Takehiko Nishio Naoko Tokunaga (née Nakajima) Masaji Kondo and Yoshimori Omote pg 2921; DOI: 10.1039/P19880002921 |
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Synthesis of carbocyclic nucleosides: preparation of (–)-5-homoaristeromycin and analogues Martin F. Jones and Stanley M. Roberts pg 2927; DOI: 10.1039/P19880002927 |
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Chemistry of 6H-pyrido[4,3-b]carbazoles. Part 12. Synthesis of potential bisintercalating drugs bearing two ellipticine units Andrew J. Ratcliffe Malcolm Sainsbury Andrew D. Smith and David I. C. Scopes pg 2933; DOI: 10.1039/P19880002933 |
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Chemistry of 6H-pyrido[4,3-b]carbazoles. Part 13. Syntheses of ring-A- and ring-D-substituted ellipticines Malcolm Sainsbury Andrew D. Smith Kuok K. Vong and David I. C. Scopes pg 2945; DOI: 10.1039/P19880002945 |
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Syntheses and alkaline hydrolyses of 2,2-imino- and 2,2-(substituted imino)-1-(2-deoxy--D-arabinofuranosyl)uracils Katsumaro Minamoto Kishiko Azuma Toshihiro Tanaka Hiroshi Iwasaki Shoji Eguchi Shizuo Kadoya and Reimei Moroi pg 2955; DOI: 10.1039/P19880002955 |
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Total synthesis of ()-pentalenene, ()-pentalenic acid, and ()deoxypentalenic acid through an intramolecular double Michael reaction Masataka Ihara Mamoru Katogi Keiichiro Fukumoto and Tetsuji Kametani pg 2963; DOI: 10.1039/P19880002963 |
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Acyl transfer reactions with phosphine oxides: synthesis of E-homoallylic alcohols, cyclopropyl ketones, and -hydroxy ketones Paul Wallace and Stuart Warren pg 2971; DOI: 10.1039/P19880002971 |
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The synthesis of a conjugate of progesterone with Lucifer Yellow VS: a potential probe for fluoroimmunoassay of steroids David N. Kirk and Barry W. Miller pg 2979; DOI: 10.1039/P19880002979 |
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Synthesis of conjugates of 11-hydroxyprogesterone with -nicotinamide adenine dinucleotide (-NAD) and adenosine triphosphate (ATP) David N. Kirk and Barry W. Miller pg 2983; DOI: 10.1039/P19880002983 |
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Cyclophilic reactions of allene-1,3-dicarboxylic ester. Part 7. Synthesis of bicyclic and tricyclic heterocyclic compounds involving nitrogen, sulphur, and carbon as nucleophiles Gurinder J. S. Doad Dorcas I. Okor Feodor Scheinmann Paul A. Bates and Michael B. Hursthouse pg 2993; DOI: 10.1039/P19880002993 |
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Synthesis of linear ethyl 9-methoxy-1H-benz[f]indole-2-carboxylate Yasuoki Murakami Toshiko Watanabe and Hisashi Ishii pg 3005; DOI: 10.1039/P19880003005 |
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Synthesis, spontaneous racemization, and photoisomerization of benzo[e]pyrene 9,10-oxide Shiv K. Agarwal Derek R. Boyd Robert Dunlop and W. Brian Jennings pg 3013; DOI: 10.1039/P19880003013 |
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Reactions of thionyl chloride with C-methyl heterocycles. Part 1. The formation of dichloro(2-quinolyl)methanesulphenyl chlorides from 2-methylquinolines Adnan H. M. Al-Shaar David W. Gilmour David J. Lythgoe Ian McClenaghan and Christopher A. Ramsden pg 3019; DOI: 10.1039/P19880003019 |
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Reactions of thionyl chloride with C-methyl heterocycles. Part 2. The formation of [1,2]dithiolo[3,4-c]quinolin-1-ones and bis[dichloro(4-quinolyl)methyl]trisulphanes from 4-methylquinolines Adnan H. M. Al-Shaar David J. Lythgoe Ian McClenaghan and Christopher A. Ramsden pg 3025; DOI: 10.1039/P19880003025 |
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Selective preparation and cyclization of 2-(2-hydroxyphenyl)-2-(isopropylthio)ethanols. New synthesis of 1-benzofurans Tomomi Ota Shun Hasegawa Seiichi Inoue and Kikumasa Sato pg 3029; DOI: 10.1039/P19880003029 |
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Synthesis of the C-glycoside fragment of nogalamycin and some nogalamycin precursors Mark A. Bates Peter. G. Sammes and Gordon A. Thomson pg 3037; DOI: 10.1039/P19880003037 |
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-Oxyiminophosphonates: chemical and physical properties. Reactions, theoretical calculations, and X-ray crystal structures of (E) and (Z)-dimethyl -hydroxyiminobenzylphosphonates Eli Breuer Rafik Karaman Amiram Goldblum Dan Gibson Haim Leader Barry V. L. Potter and Jane H. Cummins pg 3047; DOI: 10.1039/P19880003047 |
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Corrigenda Alan B. Turner Philip T. van Leersum Doreen M. Ashworth John A. Robinson and David L. Turner pg 3059; DOI: 10.1039/P19880003059 |
Issue 12
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Index pages pg A001; DOI: 10.1039/P198800BA001 |
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Front cover pg X045; DOI: 10.1039/P198800FX045 |
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Contents pages pg P047; DOI: 10.1039/P198800FP047 |
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Back cover pg X047; DOI: 10.1039/P198800BX047 |
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Bakers' yeast mediated preparation of (S)-3-(2-furyl)-2-methylpropan-1-ol, a bifunctional chiral C5 isoprenoid synthon: synthesis of (4R,8R)-4,8-dimethyldecanal, a pheromone of Tribolium castaneum Claudio Fuganti Piero Grasselli Stefano Servi and Hans-Erik Högberg pg 3061; DOI: 10.1039/P19880003061 |
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Radical cations. Part 2. Oxidative dimerization of indolizines: a chemical and electrochemical investigation Romano Andruzzi Liberato Cardellini Lucedio Greci Pierluigi Stipa Marino Poloni and Antonio Trazza pg 3067; DOI: 10.1039/P19880003067 |
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Structural elucidation of alfalfa root saponins by mass spectrometry and nuclear magnetic resonance analysis Georges Massiot Catherine Lavaud Louisette Le Men-Olivier Georges Van Binst Stephen P. F. Miller and Henry M. Fales pg 3071; DOI: 10.1039/P19880003071 |
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Asymmetric synthesis of L-[3-11C]alanine and L-[3-11C]phenylalanine by a phase-transfer alkylation reaction Karl-Johan Fasth Gunnar Antoni and Bengt Langström pg 3081; DOI: 10.1039/P19880003081 |
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Synthesis of thyroid hormone analogues. Part 1. Preparation of 3heteroarylmethyl-3,5-di-iodo-L-thyronines via phenol–dinitrophenol condensation and relationships between structure and selective thyromimetic activity Paul D. Leeson and John C. Emmett pg 3085; DOI: 10.1039/P19880003085 |
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Synthesis of thyroid hormone analogues. Part 2. Oxidative coupling approach to SK&F L-94901 Deirdre M. B. Hickey Paul D. Leeson Steven D. Carter Michael D. Goodyear Sarah J. Jones Norman J. Lewis Ian T. Morgan M. Valerie Mullane and Jane Y. Tricker pg 3097; DOI: 10.1039/P19880003097 |
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Synthesis of thyroid hormone analogues. Part 3. Iodonium salt approaches to SK&F L-94901 Deirdre M. B. Hickey Paul D. Leeson Riccardo Novelli Virendra P. Shah Brian E. Burpitt Lynne P. Crawford Bryan J. Davies Michael B. Mitchell Kirit D. Pancholi David Tuddenham Norman J. Lewis and Clare O'Farrell pg 3103; DOI: 10.1039/P19880003103 |
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3,3-Diethoxypropyl-lithium: a masked lithium propanal homoenolate in organic synthesis José Barluenga José R. Fernández Covadonga Rubiera and Miguel Yus pg 3113; DOI: 10.1039/P19880003113 |
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Syntheses of chlorins from unsymmetrically substituted iron porphyrins Dennis H. Burns Jan-Ji Lai and Kevin M. Smith pg 3119; DOI: 10.1039/P19880003119 |
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An enantioconvergent route to carbocyclic nucleosides (–)-aristeromycin and (–)-neplanocin a via the asymmetric Diels–Alder reaction Yoshitsugu Arai Yoshikazu Hayashi Masatoshi Yamamoto Hiromitsu Takayema and Toru Koizumi pg 3133; DOI: 10.1039/P19880003133 |
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Macroheterocycles. Part 44. Facile synthesis of azacrown ethers and cryptands in a two-phase system Nikolai G. Lukyanenko Stepan S. Basok and Lyubov K. Filonova pg 3141; DOI: 10.1039/P19880003141 |
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Approach to the synthesis of side-chain eudesmanediols: synthesis of kudtriol from 1-()-santonin Ravi S. Harapanhalli pg 3149; DOI: 10.1039/P19880003149 |
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Triphenylmethane dye ethynologues with absorption bands in the near infrared Shuzo Akiyama Shin'ichi Nakatsuji Kenichiro Nakashima Mituaki Watanabe and Hiroyuki Nakazumi pg 3155; DOI: 10.1039/P19880003155 |
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Synthesis of (Z)-predominant ,-unsaturated nitriles from enone cyanohydrin diethyl phosphates: application to the synthesis of ()-nuciferal, ()-(E)- and -(Z)-nuciferol, and ()-manicone Ryuji Yoneda Shinya Harusawa and Takushi Kurihara pg 3163; DOI: 10.1039/P19880003163 |
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Preparation, properties, and some chemical reactions of phenaleno[1,9-bc]furan Gamini Weeratunga Mona Austrup and Russell Rodrigo pg 3169; DOI: 10.1039/P19880003169 |
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Latent inhibitors. Part 4. Irreversible inhibition of dihydro-orotate dehydrogenase by hydantoins derived from amino acids Ian G. Buntain Colin J. Suckling and Hamish C. S. Wood pg 3175; DOI: 10.1039/P19880003175 |
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Biosynthesis of the polyether antibiotic monensin-A. Results from the incorporations of labelled acetate and propionate as a probe of the carbon chain assembly processes Gulshan R. Sood Doreen M. Ashworth Abid A. Ajaz and John A. Robinson pg 3183; DOI: 10.1039/P19880003183 |
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Butyrate metabolism in streptomycetes. Characterization of an intramolecular vicinal interchange rearrangement linking isobutyrate and butyrate in Streptomyces cinnamonensis Kevin A. Reynolds David O'Hagan David Gani and John A. Robinson pg 3195; DOI: 10.1039/P19880003195 |
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Convenient syntheses of the naturally occurring benzo[b]xanthen-12-one bikaverin. X-Ray crystallographic confirmation of the product regiochemistry Charles B. de Koning Robin G. F. Giles Lutz M. Engelhardt and Allan H. Whitet pg 3209; DOI: 10.1039/P19880003209 |
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Spirocyclic -oxo sulphoxides and sulphones as potential aldose reductase inhibitors Michael T. Cox Andrew A. Godfrey and Craig M. Ridsdale pg 3217; DOI: 10.1039/P19880003217 |
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Studies on a new route to ()-copaene and ()-ylangene David A. Archer Steven M. Bromidge and Peter G. Sammes pg 3223; DOI: 10.1039/P19880003223 |
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A novel, simple method for the preparation of hindered diphenyl ethers Peter G. Sammes Dean Thetford and Martyn Voyle pg 3229; DOI: 10.1039/P19880003229 |
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1,3-Dipolar cycloadditions of 1-(N-arylidene)amino-1, 2,3-triazoles with diphenylnitrilimine Anka Bojilova Nestor A. Rodios and Nicholas E. Alexandrou pg 3233; DOI: 10.1039/P19880003233 |
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Synthesis of new nitro and amino sterols; potential inhibitors of 4-methyl sterol oxidase I. Victor Ekhato and Cecil H. Robinson pg 3239; DOI: 10.1039/P19880003239 |
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Synthesis of 1-(3-dimethylaminopropyl)-2-substituted spiro[cycloalkane-1,3indolines] José-Gonzalo Rodriguez and Fernando Temprano pg 3243; DOI: 10.1039/P19880003243 |
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Diels-Alder reactivity of pyrano[3,4-b]indol-3-ones. Part 3. Intramolecular Diels-Alder reactions Christopher J. Moody Pritom Shah and Philip Knowles pg 3249; DOI: 10.1039/P19880003249 |
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Steroidal N-nitroamines. Part 4. Intramolecular functionalization of N-nitroamine radicals: synthesis of 1,4-nitroimine compounds Pedro de Armas Cosme G. Francisco Rosendo Hernández José A. Salazar and Ernesto Suárez pg 3255; DOI: 10.1039/P19880003255 |
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Photochemistry of N-heterocycles. Part 1. Synthesis and photochemistry of some 2(4),5-dihydro-1,2,4-triazines. X-Ray molecular structure of 1-(4-methyl-3,5,6-triphenyl-1,4,5,6-tetrahydro-1,2,4-triazin-6-yl)ethanol József Nagy József Nyitrai Pál Kolonits Károly Lempert Anna Gergely László Párkányi and Alajos Kálmán pg 3267; DOI: 10.1039/P19880003267 |
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Incorporation of [1,2-13C2]cadaverine and the enantiomeric [1-2H]cadaverines into the quinolizidine alkaloids in Baptisia australis Alison M. Fraser David J. Robins and Gary N. Sheldrake pg 3275; DOI: 10.1039/P19880003275 |
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The reaction of alkyl-substituted thioanisoles with PCl3 and AlCl3: a route to [1,2,3]benzothiadiphospholo[2,3-b][1,2,3]benzothiadiphosphole derivatives Graziano Baccolini Elisabetta Mezzina and Paolo Edgardo Todesco pg 3281; DOI: 10.1039/P19880003281 |
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Both-faces hindered porphyrins. Part 5. Synthesis and characterization of iron(III) basket handle porphyrins having multiple secondary amide groups inserted in the superstructures Philippe Maillard Corinne Schaeffer Christiane Huel Jean-Marc Lhoste and Michel Momenteau pg 3285; DOI: 10.1039/P19880003285 |
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Synthesis of thiodisaccharides using phase-transfer catalysis Francoise Chrétien Pierre Di Cesare and Bernard Gross pg 3297; DOI: 10.1039/P19880003297 |
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Polyhalogenoaromatic compounds. Part 53. Substitution in polyfluoroaromatic compounds by bulky nucleophiles Catherine L. Cheong and Basil J. Wakefield pg 3301; DOI: 10.1039/P19880003301 |
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Synthesis and photochemistry of 3,6-difluoro-10,11-benzopentacyclo [6,4,0.0,0.0]dodeca-4,10-diene Masaru Kimura Hisatoshi Kura Kastumi Nukada Hideki Okamoto Kyosuke Satake and Shiro Morosawa pg 3307; DOI: 10.1039/P19880003307 |
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Cyclic guanidines. Part 2. Rearrangement of N-substituted 2-arylamino-4,5,6,7-tetrahydro-1H-1,3-diazepines. X-Ray molecular structure of 1-(2,6-dichlorophenyl)-2-(2-methylallylimino)hexahydro-1,3-diazepine Franz Esser Klaus Brandt Karl-Heinz Pook Hans-Joachim Förster Herbert Köppen Jean-Michel Leger and Alain Carpy pg 3311; DOI: 10.1039/P19880003311 |
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Antifertility agents: a synthetic entry to yuehchukene analogues; stereoselective synthesis of 7,7-bis-nor-yuehchukene via 9-methyl-6-oxo-6a-7,8,10a-tetrahydroindeno[2,1-b]indole Kin-Fai Cheng Tin-Tau Chan Ting-Fong Lai and Yun-Cheung Kong pg 3317; DOI: 10.1039/P19880003317 |
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Oligomeric flavanoids. Part 3. Structure and synthesis of phlobatannins related to (–)-fisetinidol-(4,6)- and (4,8)-(+)-catechin profisetinidins Jan P. Steynberg Johann F. W. Burger Desmond A. Young Edward V. Brandt Jacobus A. Steenkamp and Daneel Ferreira pg 3323; DOI: 10.1039/P19880003323 |
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Oligomeric flavanoids. Part 4. Base-catalysed conversions of (–)-fisetinidol-(+)-catechin profisetinidins with 2,3-trans-3,4-cis-flavan-3-ol constituent units Jan P. Steynberg Johann F. W. Burger Desmond A. Young Edward V. Brandt Jacobus A. Steenkamp and Daneel Ferreira pg 3331; DOI: 10.1039/P19880003331 |
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Chloromethyl-lithium and 1-chloro-2-methylprop-1-enyl-lithium: useful intermediates in the synthesis of unsaturated and bifunctionalized compounds José Barluenga José L. Fernández-Simón José M. Concellón and Miguel Yus pg 3339; DOI: 10.1039/P19880003339 |
A convenient method for S-glycosidic bond formation. Synthesis of p-lodophenyl 4-thiomaltotrioside and its 2 ,3-unsaturated analogueMichèle Blanc-Muesser and Hugues Driguez pg 3345; DOI: 10.1039/P19880003345 |
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Synthesis of ketofuranosides by epoxidation-ring closure of enol ethers Anna Boschetti Luigi Panza Fiamma Ronchetti Giovanni Russo and Lucio Toma pg 3353; DOI: 10.1039/P19880003353 |
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Studies related to penicillins. Part 27. A strategy for the conversion of 1,1-dioxides of penicillanates into 1,1-dioxides of 3-methylceph-3-em-4-carboxylates G. D. Sriyani Ananda and Richard J. Stoodley pg 3359; DOI: 10.1039/P19880003359 |
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Synthesis and reactivity of lithiated -functionalised ketene dithioacetals. Generation of a flexible -lithioacrylate equivalent Edward Dziadulewicz David Hodgson and Timothy Gallagher pg 3367; DOI: 10.1039/P19880003367 |
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Thermal fragmentation of 2-azidobenzo[b]thiophene in the presence of alkenes: a new synthetic route to 1-(2-benzo[b]thienyl)aziridines and/or thiochroman-4-carbonitriles Piero Spagnolo and Paolo Zanirato pg 3375; DOI: 10.1039/P19880003375 |
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Synthesis and thermal reactions of 1,2-dihydro-1,2,4-benzotriazines Frank D. King pg 3381; DOI: 10.1039/P19880003381 |
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Resolution of bicyclo[3.2.0]hept-2-en-6-ols and bicyclo[4.2.0]oct-2-en-endo-7-ol using lipases Ian C. Cotterill Emma L. A. Macfarlane and Stanley M. Roberts pg 3387; DOI: 10.1039/P19880003387 |
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Higher-carbon sugars. Part 12. The synthesis of new octitols from D-glucose and D-mannose via the osmylation of unsaturated precursors John C. Barnes John S. Brimacombe Abul K. M. S. Kabir and Timothy J. R. Weakley pg 3391; DOI: 10.1039/P19880003391 |
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Photochemistry of 2-substituted 1,2,3,4-tetrahydronaphthalene-1-spiro-3oxaziridines. Variable-temperature 1H nuclear magnetic resonance spectroscopy of 1-substituted 1,3,4,5-tetrahydro-2H-1-benzazepin-2-ones Graham P. Johnson and Brian A. Marples pg 3399; DOI: 10.1039/P19880003399 |